Diaquabis(2-chlorobenzoato-?O)bis-(N,N-diethylnicotinamide-?N1)manganese(II)
Küçük Resim Yok
Tarih
2009
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Int Union Crystallography
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
In the monomeric title complex, [Mn(C7H4ClO2)(2)(C10H14N2O)(2)(H2O)(2)], the Mn-II atom is located on a crystallographic centre of inversion. The asymmetric unit contains one 2-chlorobenzoate (CB) ligand, one diethylnicotinamide (DENA) ligand and one coordinated water molecule, all ligands being monodentate. The four O atoms in the equatorial plane around the Mn atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the DENA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 77.9 (11)degrees, while the pyridine and benzene rings are oriented at a dihedral angle of 45.94 (5)degrees. In the crystal structure, intermolecular O-H center dot center dot center dot O hydrogen bonds link the molecules into infinite chains.
Açıklama
Anahtar Kelimeler
Molecular-Structure, Crystal
Kaynak
Acta Crystallographica Section E-Crystallographic Communications
WoS Q Değeri
Q4
Scopus Q Değeri
Q3
Cilt
65
