Hydro/ solvothermal synthesis and crystal structure of new ni(ii) coordination polymer containing pamoic acid and ethylenediamine mixed ligands : {[ni(µ-pam)(en)2]·h2o}n
Küçük Resim Yok
Tarih
2017
Yazarlar
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Yayıncı
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
The new coordination polymers arranged from flexible pamoic acid, namely {[Ni(µ-pam)(en)2]·H2O}n (1), (H2pam= pamoic acid, en= ethylenediamine), have been synthesized under hydro/ solvothermal conditions and characterized by elemental analysis, simultaneous TG, DTA techniques, IR spectroscopy, and X-ray crystallography. X-ray single crystal structure analysis of 1 shows that the Ni(II) ions are bridged by pamoic acid ligands to generate 1-dimensional (1D) coordination polymer running parallel to the direction, with the Ni???Ni separation is 14.057 Å. Adjacent 1D chains are connected by N-H???O and O-H???O hydrogen bonds to establishing 3 dimensional (3D) supramolecular network
Açıklama
Anahtar Kelimeler
Mühendislik, Kimya
Kaynak
Journal of the Turkish Chemical Society, Section A: Chemistry
WoS Q Değeri
Scopus Q Değeri
Cilt
4
Sayı
3
