Diaquabis(2-bromobenzoato-?O)bis(nicotinamide-?N1)nickel(II)

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dc.authoridOzturkkan, Fureya Elif/0000-0001-6376-4161
dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.contributor.authorHokelek, Tuncer
dc.contributor.authorYilmaz, Filiz
dc.contributor.authorTercan, Baris
dc.contributor.authorOzbek, F. Elif
dc.contributor.authorNecefoglu, Hacali
dc.date.accessioned2024-09-29T16:03:14Z
dc.date.available2024-09-29T16:03:14Z
dc.date.issued2009
dc.departmentKarabük Üniversitesien_US
dc.description.abstractThe title Ni-II complex, [Ni(C7H4BrO2)(2)(C6H6N2O)(2)(H2O)(2)], is centrosymmetric. It contains two 2-bromobenzoate (BB) ligands, two nicotinamide (NA) ligands and two water molecules, all of them being monodentate. The four O atoms in the equatorial plane around the Ni atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 30.81 (17)degrees, while the pyridine and benzene rings are oriented at a dihedral angle of 84.66 (6)degrees. In the crystal structure, O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds link the molecules into a supramolecular structure. A weak C-H center dot center dot center dot pi interaction is also found.en_US
dc.identifier.doi10.1107/S1600536809021710
dc.identifier.endpageU749en_US
dc.identifier.issn2056-9890
dc.identifier.pmid21582699en_US
dc.identifier.scopus2-s2.0-67650822797en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpageM768en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536809021710
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5977
dc.identifier.volume65en_US
dc.identifier.wosWOS:000267385300057en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Crystallographic Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectMolecular-Structureen_US
dc.subjectCrystalen_US
dc.titleDiaquabis(2-bromobenzoato-?O)bis(nicotinamide-?N1)nickel(II)en_US
dc.typeArticleen_US

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