Hokelek, TuncerSaglam, Ertugrul GaziTercan, BarisAybirdi, OzgurNecefoglu, Hacali2024-09-292024-09-2920102056-9890https://doi.org/10.1107/S1600536810046854https://hdl.handle.net/20.500.14619/6020In the centrosymmetric title structure, [Zn(C9H10NO2)(2)(C6H6N2O)(2)(H2O)(2)]-2H(2)O, the Zn II cation, located on an inversion center, is coordinated by two 4-(methylamino) benzoate anions, two nicotinamide ligands and two water molecules in a slightly distorted octahedral geometry. The dihedral angle between the carboxylate group and the attached benzene ring is 3.09 (9)degrees, while the pyridine and benzene rings are oriented at a dihedral angle of 77.10(4)degrees. The uncoordinated water molecule is linked to nicotinamide ligands by O-H center dot center dot center dot O hydrogen bonds. In the crystal, intermolecular N-H center dot center dot center dot O, O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds link the molecules into a three-dimensional network. A weak N-H center dot center dot center dot pi interaction also occurs.eninfo:eu-repo/semantics/openAccessArticle10.1107/S16005368100468542-s2.0-78650149488U140321589309Q3M163666WOS:000284831000108Q4