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Öğe Application of Natural Coagulants for Pharmaceutical Removal from Water and Wastewater: A Review(Mdpi, 2022) Alazaiza, Motasem Y. D.; Albahnasawi, Ahmed; Ali, Gomaa A. M.; Bashir, Mohammed J. K.; Nassani, Dia Eddin; Al Maskari, Tahra; Amr, Salem S. AbuPharmaceutical contamination threatens both humans and the environment, and several technologies have been adapted for the removal of pharmaceuticals. The coagulation-flocculation process demonstrates a feasible solution for pharmaceutical removal. However, the chemical coagulation process has its drawbacks, such as excessive and toxic sludge production and high production cost. To overcome these shortcomings, the feasibility of natural-based coagulants, due to their biodegradability, safety, and availability, has been investigated by several researchers. This review presented the recent advances of using natural coagulants for pharmaceutical compound removal from aqueous solutions. The main mechanisms of natural coagulants for pharmaceutical removal from water and wastewater are charge neutralization and polymer bridges. Natural coagulants extracted from plants are more commonly investigated than those extracted from animals due to their affordability. Natural coagulants are competitive in terms of their performance and environmental sustainability. Developing a reliable extraction method is required, and therefore further investigation is essential to obtain a complete insight regarding the performance and the effect of environmental factors during pharmaceutical removal by natural coagulants. Finally, the indirect application of natural coagulants is an essential step for implementing green water and wastewater treatment technologies.Öğe The effectiveness of rosehip seeds powder as a plant-based natural coagulant for sustainable treatment of steel industries wastewater(Desalination Publ, 2022) Abujazar, Mohammed Shadi S.; Karaagac, Sakine Ugurlu; Abu Amr, Salem S.; Fatihah, Suja; Bashir, Mohammed J. K.; Alazaiza, Motasem Y. D.; Ibrahim, EimanThis study aims to investigate the performance plant-based natural coagulant from rosehip seed powder in the treatment of iron and steel factory wastewater. The concentrations of COD, total suspended solids (TSS), ammonia-nitrogen (NH3-N), manganese (Mn), iron (Fe), zinc (Zn), aluminum (Al), and nickel ( Ni) in effluent wastewater were examined. Coagulation investigations were carried out using an orbital shaker and a flocculation apparatus to investigate the effects of iron and steel factory effluent, pH, and rosehip seeds powder dosage on coagulation efficacy. The rosehip powder removes a large amount of COD, TSS, NH3-N, Mn, Fe, Zn, Al, and Ni from effluent at pH 8 with percentages of 86.1%, 99%, 79%, 86%, 91.7%, 90.6%, 73.7%, and 100%, respectively, at 1 g/L. The effects of pH ranges ranging from (5-10) reveal that the wastewater sample's natural pH (8) demonstrates the maximum practicable removal effectiveness. FTIR analysis revealed the presence of numerous functional groups involved in the coagulation process. One may argue that rosehip seed powder holds great potential as a natural plant-based coagulant for water treatment and could be used to treat effluent from iron and ste el factories.Öğe Factorial design and optimization of pinecone seed powder as a natural coagulant for organic and heavy metals removal from industrial wastewater(Desalination Publ, 2023) Abujazar, Mohammed Shadi S.; Karaagac, Sakine Ugurlu; Abu Amr, Salem S.; Fatihah, Suja; Bashir, Mohammed J. K.; Alazaiza, Motasem Y. D.; Yusof, ArijVarious chemical coagulants have previously been used for wastewater treatment with substantial efficacy in eliminating heavy metals and other criteria. However, their economic effectiveness and the remnant of harmful chemical precipitates that pose hazards to human health and the environment. As a result, utilizing plant-based natural coagulants is seen as an alternative non-toxic, biodegradable, and ecologically beneficial strategy. This study aims to investigate the performance of pinecone seed powder as a natural coagulant in iron and steel factory wastewater treatment, as well as to optimize the operating parameters to determine the feasibility of employing pinecone seed powder in wastewater treatment. Using 0.6 g/200 mL pinecone as a controlling factor, pH, and settling time, the response surface methodology, a statistical experimental design was utilized to increase the chemical oxygen demand (COD), ammoniacal nitrogen (NH3-N), and heavy metals removal effimodels for the parameters specified were determined to be significant with a low probability.Öğe Factorial design and optimization of thermal activation of persulfate for stabilized leachate treatment(Desalination Publ, 2022) Chin, Yun Tong; Bashir, Mohammed J. K.; Abu Amr, Salem S.; Alazaiza, Motasem Y. D.Landfill remains as the most common municipal waste disposal method in the world. However, the production of leachate associate with landfill persists as a major drawback, which bring harmful effect to the environment. Persulfate oxidation is recently used for stabilized leachate treatment. Persulfate alone is still limited for leachate oxidation and an activation method is required to improve its performance. Accordingly, this study aims to investigate and compare the performance of per sulfate subjected to thermal activation in treating stabilized leachate. Different experimental operational factors were considered and evaluated such as, S2O82-/chemical oxygen demand (COD) ratio, temperature, and reaction time. Experiments were designed and optimized by using response surface methodology, and results were analysed by using analysis of variance. The removal efficiencies for COD and colour using inactivation persulfate were reported only at 14% and 29%, respectively. However, the efficiencies were improved to 93.39% and 94.00% for COD and colour after thermal activation of persulfate under an optimum condition of 10 S2O82-/COD ratio, 80 degrees C and 120 min. The maximum efficiency was achieved at the treatment cost of RM0.66 per litre of leachate.Öğe Nanoscale zero-valent iron application for the treatment of soil, wastewater and groundwater contaminated with heavy metals: a review(Desalination Publ, 2022) Alazaiza, Motasem Y. D.; Albahnasawi, Ahmed; Copty, Nadim K.; Bashir, Mohammed J. K.; Nassani, Dia Eddin; Al Maskari, Tahra; Abu Amr, Salem S.Nanoscale zero-valent iron (nZVI) has been extensively investigated for the remediation of soil, wastewater, and groundwater contaminated with heavy metals. This paper presents a collective review of nZVI synthesis, nZVI interaction mechanisms with heavy metals, factors affecting nZVI reactivity, recent applications of nZVI for heavy metals removal, and the environmental concerns of nZVI application for soil microorganisms and plants. Modified nZVI, spatially biochar supported nZVI (BC@nZVI) and sulfidation nanoscale zero-valent iron (S-nZVI) showed high heavy metals removal efficiency and more stable performance compared to nZVI alone. The removal of heavy metals by nZVI is as a synergistic process where adsorption, oxidation/reduction and precipitation occur simultaneously or in series. pH and organic matter are the main factors that significantly affect nZVI reactivity. Toxic effects of nZVI are observed for the soil microorganisms as the direct contact may cause a decrease in cell viability and membrane damage. A low concentration of nZVI promotes the growth of plant whereas high concentration decreases root length. It is observed that, further research is needed to enhance nZVI recovery techniques, evaluate the effectiveness of novel modified nZVI and their effects on the environment, and the full-scale application of nZVI.Öğe Recent advancement in the application of hybrid coagulants in coagulation-flocculation of wastewater: A review(Elsevier Sci Ltd, 2022) Abujazar, Mohammed Shadi S.; Karaagac, Sakine Ugurlu; Abu Amr, Salem S.; D Alazaiza, Motasem Y.; Bashir, Mohammed J. K.Hybrid coagulants have recently received attention in water and wastewater treatment technologies mainly due to their cost-efficiency and exceptional performance. As such, this study highlights the recent advanced appli-cations of hybrid coagulants in wastewater treatment. The materials used for hybrid coagulants, such as those hybridised in chemical bond, structurally-hybridised, and functionally-hybridised under certain combination techniques (e.g., organic/inorganic, organic/organic, inorganic/inorganic, organic/natural polymer, inorganic/ natural polymer, organic/biopolymer, & inorganic/biopolymer), were evaluated and compared based on their applications on different type of wastewaters, experimental conditions, and treatment efficiency. The perfor-mance of inorganic/inorganic hybrid coagulation demonstrated high removal of turbidity (98.5%), chemical oxygen demand (COD) (73.3%), heavy metals (99.2%), and colour (98%) -seemingly better than organic removal efficiency. The optimum operational conditions for inorganic/organic coagulants at varied pH levels (6-12) lowered the cost for chemicals used for pH adjustment in treating industrial wastewater. Referring to the review outcomes, hybrid coagulation applications are indeed efficient for treatment of highly concentrated in-dustrial wastewater, such as oily wastewater.Öğe Recent Advances of Nanoremediation Technologies for Soil and Groundwater Remediation: A Review(Mdpi, 2021) Alazaiza, Motasem Y. D.; Albahnasawi, Ahmed; Ali, Gomaa A. M.; Bashir, Mohammed J. K.; Copty, Nadim K.; Abu Amr, Salem S.; Abushammala, Mohammed F. M.Nanotechnology has been widely used in many fields including in soil and groundwater remediation. Nanoremediation has emerged as an effective, rapid, and efficient technology for soil and groundwater contaminated with petroleum pollutants and heavy metals. This review provides an overview of the application of nanomaterials for environmental cleanup, such as soil and groundwater remediation. Four types of nanomaterials, namely nanoscale zero-valent iron (nZVI), carbon nanotubes (CNTs), and metallic and magnetic nanoparticles (MNPs), are presented and discussed. In addition, the potential environmental risks of the nanomaterial application in soil remediation are highlighted. Moreover, this review provides insight into the combination of nanoremediation with other remediation technologies. The study demonstrates that nZVI had been widely studied for high-efficiency environmental remediation due to its high reactivity and excellent contaminant immobilization capability. CNTs have received more attention for remediation of organic and inorganic contaminants because of their unique adsorption characteristics. Environmental remediations using metal and MNPs are also favorable due to their facile magnetic separation and unique metal-ion adsorption. The modified nZVI showed less toxicity towards soil bacteria than bare nZVI; thus, modifying or coating nZVI could reduce its ecotoxicity. The combination of nanoremediation with other remediation technology is shown to be a valuable soil remediation technique as the synergetic effects may increase the sustainability of the applied process towards green technology for soil remediation.Öğe Thermal based remediation technologies for soil and groundwater: a review(Desalination Publ, 2022) Alazaiza, Motasem Y. D.; Albahnasawi, Ahmed; Copty, Nadim K.; Ali, Gomaa A. M.; Bashir, Mohammed J. K.; Al Maskari, Tahra; Abu Amr, Salem S.Thermal remediation technologies are fast and effective tools for the remediation of contaminated soils and sediments. Nevertheless, the high energy consumption and the effect of high temperature on the soil properties may hinder the wide applications of thermal remediation methods. This review highlights the recent studies focused on thermal remediation. Eight types of thermal remediation processes are discussed, including incineration, thermal desorption, stream enhanced extraction, electrical resistance heating, microwave heating, smoldering, vitrification, and pyrolysis. In addition, the combination of thermal remediation with other remediation technologies is presented. Finally, thermal remediation sustainability is evaluated in terms of energy efficiency and their impact on soil properties. The developments of the past decade show that thermal-based technologies are quite effective in terms of contaminant removal but that these technologies are associated with high energy use and costs and can has an adverse impact on soil properties. Nonetheless, it is anticipated that continued research on thermally based technologies can increase their sustainability and expand their applications. Low temperature thermal desorption is a promising remediation technology in terms of land use and energy cost as it has no adverse effect on soil function after treatment and low temperature is required. Overall, selecting the sustainable remediation technology depends on the contaminant properties, soil properties and predicted risk level.