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Öğe Characteristics and high temperature wear behavior of chrome vanadium carbide composite coatings produced by thermo-reactive diffusion(Elsevier Science Sa, 2020) Gunen, Ali; Kalkandelen, Muge; Gok, Mustafa Sabri; Kanca, Erdogan; Kurt, Bulent; Karakas, Mustafa Serdar; Karahan, Ismail HakkiIn this study, Cr-V-C composite carbide layers were grown on the surface of a GGG-80 ductile iron using thermoreactive diffusion (TRD). The TRD process was carried out at temperatures of 900, 1000, and 1100 degrees C for 1 h using nano-sized Fe-V and Fe-Cr powders. The coatings were characterized by X-ray diffractometry (XRD), 2D profilometry, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), microhardness measurements, nanoindentation, and wear tests. The wear tests were performed on untreated and coated samples using a ball-on-disc type wear tester under 10 N load at four different temperatures (25 degrees C, 250 degrees C, 500 degrees C and 750 degrees C) against a 6-mm WC ball. Metallographic investigations revealed that the graphite nodules near the surface were dissolved as a result of the TRD process. Depending on the TRD process temperature, a coating with a thickness of 12-36 mu m, hardness of 24.14-31.38 GPa, and elastic modulus of 198-233 GPa was obtained. An increase in process temperature increased the thickness, hardness, and elastic modulus of the obtained Cr-V-C layers, which resulted in low friction coefficient values and decreased wear rates. Although all coated samples showed improved wear resistance in all wear test conditions, the wear rates were significantly increased at 750 degrees C due to flaking.Öğe Characteristics, high temperature wear and oxidation behavior of boride layer grown on nimonic 80A Ni-based superalloy(Elsevier Science Sa, 2021) Gunen, Ali; Doleker, Kadir Mert; Korkmaz, Mehmet Erdi; Gok, Mustafa Sabri; Erdogan, AzmiNickel-based superalloy Nimonic 80A was pack-borided in a solid medium at temperatures of 850 degrees C and 950 degrees C for 2 h and 4 h using silicon-free boriding powders. To investigate the effects of the boriding treatments on mechanical properties (hardness, modulus of elasticity, fracture toughness) and high temperature oxidation resistance, the layers grown on the surfaces were characterized using optical and scanning electron microscopy, energy dispersive spectroscopy, and X-ray diffractometry, and evaluated using microhardness, nanoindentation, wear and oxidation tests. Wear tests were performed on untreated and borided Nimonic 80A alloys using a ball-on-disc tribometer at room temperature and at 500 degrees C under dry sliding conditions. Oxidation tests were carried out in air at 1000 degrees C for 5 h, 25 h and 75 h. Characterization studies revealed a smooth, 22 to 86 mu m thick crack-free boride layer consisting mainly of Ni2B and minor quantities of CrB, Cr2B and Cr5B3 in the borided samples. The hardness and elastic modulus of the boride layer was measured as 15.57-18.95 GPa and 142-217 GPa, respectively. Increasing the boriding temperature and time increased the concentrations of chromium in the boride layer. The hardness and elastic modulus of the boride layer increased with chromium content while its fracture toughness decreased. The boriding treatments improved the dry sliding wear resistance. Increasing boriding time and temperature generally led to a higher wear resistance values. However, the treatments had no significant effect on oxidation resistance. The results of this study show that boriding can significantly improve the wear resistance of Nimonic 80A without compromising its oxidation resistance.Öğe The Effect of Cutting Parameters on Tool Wear During the Milling of Carbon Fiber Reinforced Polymer (CFRP) Composites(Kaunas Univ Tech, 2019) Ozkan, Dervis; Gok, Mustafa Sabri; Gokkaya, Hasan; Karaoglanli, Abdullah CahitReduction of machining times and optimization of cutting parameters and conditions hold great importance in machining processes. Milling is among the most important machining processes used for machining of fiber-reinforced composite materials. The present research was carried out to investigate the effect of cutting parameters on tool wear during the milling of carbon fiber reinforced polymer (CFRP) materials which are widely used in aviation and aerospace industries. A multi-directional CFRP composite material with 6 mm width and 26 layers was used as the workpiece. The tests were performed under dry conditions on a CNC vertical processing center with 100, 200 and 300 m/min cutting speeds; 0.05 , 0.15 and 0.25 mm/tooth feedrates and at 1 mm constant cutting width. To understand the wear process, scanning electron microscopy (SEM) analyses of the worn surfaces were performed.Öğe Effect of thermal degradation on the properties and wear behavior of Cr-V-C composite coatings grown on ductile iron(Elsevier Science Sa, 2021) Gunen, Ali; Kanca, Erdogan; Karakas, Mustafa Serdar; Gok, Mustafa Sabri; Kalkandelen, Muge; Kurt, Bulent; Cetin, MelikThe thermal fatigue behavior of chromium vanadium carbide (Cr - V - C) coatings and the wear of the coatings after thermal fatigue cycling was studied. The Cr - V - C coatings were grown on the surface of a ductile iron using thermo-reactive diffusion (TRD) and subjected to thermal fatigue in the temperature range of 25 to 750 degrees C for up to 500 cycles. Characterizations were made using scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, microhardness measurements and wear tests. The Cr - V - C coated samples displayed superior thermal fatigue and wear resistance compared to the untreated ductile iron, mainly due to the dissolution of graphite nodules in the vicinity of the surface during TRD. The dissolution of graphite reduced the possibility of failure initiating from graphite nodules and graphite-matrix interfaces. Increasing the number of cycles resulted in increased flaking and decreased wear resistance in both the Cr - V - C coatings as well as the untreated ductile iron. Although much of the Cr V C coating was lost (due to flaking) after thermal cycling, the absence of graphite near the surface still provided improved resistance to wear in the TRD-treated samples. The results of this study indicate that TRD coatings hold great promise for use in the industrial applications.Öğe Low-temperature aluminizing influence on degradation of nimonic 80A surface: Microstructure, wear and high temperature oxidation behaviors(Elsevier, 2021) Erdogan, Azmi; Yener, Tuba; Doleker, Kadir Mert; Korkmaz, Mehmet Erdi; Gok, Mustafa SabriNimonic 80A alloy has been subjected to aluminizing process to improve its high temperature oxidation and wear properties. Pack aluminizing process was carried out for 3 and 5 h at 650 and 700 degrees C temperatures without using a protective atmosphere. Aluminising treatment was carried out using metallic aluminium, ammonium chloride (NH4Cl) and alumina as a filler. The morphology and structure of aluminide layers was analysed by SEM-EDS. It was observed that there was a super bonding between matrix and coating layers which are smooth, dense and porosity free. Dominant phases of Ni2Al3 and Al80Cr20 were detected by XRD analysis. Layer thickness was measured from the surface to the matrix and changed from 20 to 70 mu m which was increased with increasing process duration and temperature. The matrix hardness is 400 HVN while the hardness of coating layer raised to 1025 HVN with the process time and temperature. Wear losses decreased with the increase in coating temperature and time in both high temperature and room temperature tests. After isothermal oxidation tests at 1000 degrees C up to 75 h, all aluminized samples consist of alumina scale while Nimonic 80A consist of Cr2O3 and TiO2 mixed oxides with high thickness. The increased aluminizing temperature and time provide better protection against high temperature oxidation.Öğe Machining effects on delamination failure in milling MD-CFRPs with uncoated carbide tools(Ice Publishing, 2019) Ozkan, Dervis; Gok, Mustafa Sabri; Gokkaya, Hasan; Karaoglanli, Abdullah CahitAs one of the main failure mechanisms emerging in the milling of carbon (C)-fiber-reinforced polymer (CFRP) materials, delamination is primarily affected by cutting tool material and geometry, machining parameters and the dynamic loads arising during the machining process. In this study, machinability tests were performed without the use of coolants to examine the effect of machining parameters on multidirectional CFRP composite workpieces, which have a wide application in industries. The tests were applied on a computer numerically controlled vertical processing center at three different cutting speeds (100, 200 and 300 m/min), three different feed rates (0.05, 0.15 and 0.25 mm/tooth) and constant cutting depth (1 mm). Following the tests, the changes in the workpiece were examined in terms of surface roughness, cutting forces, tool wear and delamination failures. The average surface roughness increased with increasing feed rate. Cutting forces also increased with increasing cutting speed, which caused improvements on average surface roughness values. As a machining parameter, feed rate was found to be a determining factor in the machining of CFRP composite materials.Öğe An Overview of Utilization of Blast Furnace and Steelmaking Slag in Various Applications(Elsevier Science Bv, 2019) Oge, Mecit; Ozkan, Dervis; Celik, M. Bahattin; Gok, Mustafa Sabri; Karaoglanli, Abdullah CahitEver-increasing energy costs and environmental restrictions have compelled researchers to focus on the reutilization of vast amounts of industrial by-products such as blast furnace slag and steelmaking slag, in energy extensive and material extensive industries such as iron-steel production and construction. Attempts to reutilize these waste materials all around the world have yielded successful results up to date, such that, in some of these attempts they even surpassed their intended use as blend or replacement materials and became serious rivals to their industrial counterparts. Various ways to reutilize these waste materials have been explored up to date, including waste heat recovery, clinker substitute in cement production, and a number of comparatively more value added applications. The ongoing attempts have come to a point that pushes the limits for more technological uses such as alternative ceramic coating materials in surface engineering applications. In this regard, this review study aims to provide an overview of and a collective approach to various uses of blast furnace and steelmaking slag in diverse applications and fields, with a view to provide insight into the current attempts to optimize or improve their use, as well as emerging trends as to the potential use of these waste materials in higher value-added applications. (c) 2019 Elsevier Ltd. All rights reserved.Öğe Study of the Wear Resistance Plasma Nitrided GGG60 by Optimization of Surface Treatment Conditions Using Response Surface Methodology(Springer Int Publ Ag, 2024) Karamanli, Ismail Aykut; Gok, Mustafa Sabri; Kucuk, Yilmaz; Unal, OkanIn this study, the wear performance of spheroidal graphite cast iron subjected to plasma nitriding at different temperatures and treatment durations was investigated. The plasma nitriding parameters were optimized by response surface methodology (RSM) due to the output performance. Plasma nitriding was applied at three different temperatures (400, 450, 500 degrees C) and three different heat treatment durations (0.5, 2, 4 h). Wear tests were performed by ball-on-disk method for 60 minutes and for three different wear loads (10, 20, 30 N). The specimens were investigated for hardness, microstructure and wear performance. The RSM model was then created by using the wear resistance features. Plasma nitriding showed better wear performance than the untreated specimen for all treatment conditions. Hardness, nitrided layer thickness and wear performance remarkably improved with increasing temperature and process duration. The parameter that affects volume loss the most is wear load with 70.66% according to RSM modeling results. The most effective parameter in the wear rate change was found to be treatment duration at 42.85%. The model was able to predict the results with an error of 2.11% for volume loss and 9.14% for wear rate. The prediction results are very close to the experimental results. This clearly shows that the model can be used to determine the plasma nitriding parameters.