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Öğe Characteristics and high temperature wear behavior of chrome vanadium carbide composite coatings produced by thermo-reactive diffusion(Elsevier Science Sa, 2020) Gunen, Ali; Kalkandelen, Muge; Gok, Mustafa Sabri; Kanca, Erdogan; Kurt, Bulent; Karakas, Mustafa Serdar; Karahan, Ismail HakkiIn this study, Cr-V-C composite carbide layers were grown on the surface of a GGG-80 ductile iron using thermoreactive diffusion (TRD). The TRD process was carried out at temperatures of 900, 1000, and 1100 degrees C for 1 h using nano-sized Fe-V and Fe-Cr powders. The coatings were characterized by X-ray diffractometry (XRD), 2D profilometry, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), microhardness measurements, nanoindentation, and wear tests. The wear tests were performed on untreated and coated samples using a ball-on-disc type wear tester under 10 N load at four different temperatures (25 degrees C, 250 degrees C, 500 degrees C and 750 degrees C) against a 6-mm WC ball. Metallographic investigations revealed that the graphite nodules near the surface were dissolved as a result of the TRD process. Depending on the TRD process temperature, a coating with a thickness of 12-36 mu m, hardness of 24.14-31.38 GPa, and elastic modulus of 198-233 GPa was obtained. An increase in process temperature increased the thickness, hardness, and elastic modulus of the obtained Cr-V-C layers, which resulted in low friction coefficient values and decreased wear rates. Although all coated samples showed improved wear resistance in all wear test conditions, the wear rates were significantly increased at 750 degrees C due to flaking.Öğe Effect of thermal degradation on the properties and wear behavior of Cr-V-C composite coatings grown on ductile iron(Elsevier Science Sa, 2021) Gunen, Ali; Kanca, Erdogan; Karakas, Mustafa Serdar; Gok, Mustafa Sabri; Kalkandelen, Muge; Kurt, Bulent; Cetin, MelikThe thermal fatigue behavior of chromium vanadium carbide (Cr - V - C) coatings and the wear of the coatings after thermal fatigue cycling was studied. The Cr - V - C coatings were grown on the surface of a ductile iron using thermo-reactive diffusion (TRD) and subjected to thermal fatigue in the temperature range of 25 to 750 degrees C for up to 500 cycles. Characterizations were made using scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, microhardness measurements and wear tests. The Cr - V - C coated samples displayed superior thermal fatigue and wear resistance compared to the untreated ductile iron, mainly due to the dissolution of graphite nodules in the vicinity of the surface during TRD. The dissolution of graphite reduced the possibility of failure initiating from graphite nodules and graphite-matrix interfaces. Increasing the number of cycles resulted in increased flaking and decreased wear resistance in both the Cr - V - C coatings as well as the untreated ductile iron. Although much of the Cr V C coating was lost (due to flaking) after thermal cycling, the absence of graphite near the surface still provided improved resistance to wear in the TRD-treated samples. The results of this study indicate that TRD coatings hold great promise for use in the industrial applications.Öğe Microstructural, wear and corrosion characteristics of boronized AISI 904L superaustenitic stainless steel(Pergamon-Elsevier Science Ltd, 2021) Cetin, Melik; Gunen, Ali; Kalkandelen, Muge; Karakas, Mustafa SerdarAISI 900 series stainless steels are considered as low-cost alternatives to nickel-based superalloys used for highly corrosive environments. However, in terms of mechanical properties, they have average strength and hardness similar to other austenitic stainless steel grades and this often limits their use. If a 900 series alloy were to be used under tribocorrosive conditions, its surface properties would have to be improved by a wear and corrosion resistant coating. In this study, AISI 904L steel was pack boronized in a solid medium at temperatures of 900, 1000 and 1100 ?C for 2, 4 and 6 h with nano-sized boronizing powders. The grown boride layers were evaluated using scanning electron microscopy, energy dispersive X-ray spectroscopy, X-ray diffractometry, 2D profilometry, microhardness measurements, ball-on-disk type wear tests and electrochemical corrosion tests. Characterization studies revealed a complex boride layer consisting of FeB, Fe2B, CrB, Cr3B4, Ni3B and Mo2B phases with 2366?2396 HV hardness. Wear tests showed that the abrasive wear resistance of the AISI 904L steel was improved by up to 40 times. The corrosion resistance of boronized AISI 904L was inferior to untreated AISI 904L in 3.5% NaCl, but comparable to AISI 316L.