Role of dysprosium substitution on microscopy architecture, structural stability, and crack propagation mechanism in Bi-2212 engineering ceramics

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dc.contributor.authorKurtul G.
dc.contributor.authorUlgen A.T.
dc.contributor.authorArmagan O.
dc.contributor.authorTurkoz M.B.
dc.contributor.authorErdem I.
dc.contributor.authorYildirim G.
dc.date.accessioned2025-03-17T07:28:04Z
dc.date.available2025-03-17T07:28:04Z
dc.date.issued2025-01-28
dc.departmentFakülteler, Mühendislik Fakültesi, Elektrik-Elektronik Mühendisliği Bölümü
dc.descriptionThe authors would like to express their gratitude to Bolu Abant Izzet Baysal University Research Fund for its financial support in spectral analysis. Project Numbers: 2019.09.05.1431. Yazarlar, spektral analiz konusunda kendilerine sağladığı maddi destekten dolayı Bolu Abant İzzet Baysal Üniversitesi Araştırma Fonu'na şükranlarını sunarlar. Proje Numaraları: 2019.09.05.1431.
dc.description.abstractThis study achieves a strong link between microscopy architecture and fundamental characteristics including electrical conductivity, superconducting, and key mechanical design properties of Bi2.1-xDyxSr2.0Ca1.1Cu2.0Oy (Bi-2212) ceramic structures with different dysprosium molar ratio ranges of 0.00 ≤ x ≤ 0.10. The Dy/Bi substituted Bi-2212 ceramics are characterized by scanning electron microscopy (SEM), electrical resistivity (ρ-T), Electron Dispersive x-ray (EDX) investigations, and microindentation Vickers hardness (Hv) tests. Powder x-ray diffraction (XRD) experimental inspection is also studied to support SEM and Hv results. All experimental findings show significant improvement with an increase in the Dy impurity molar ratio to x = 0.01. On this basis, the Bi2.09Dy0.01Sr2.0Ca1.1Cu2.0Oy ceramic structure exhibits the lowest resistivity of 8.95 mΩ.cm at 300 K and transition width of 4.75 K, and the highest T c o n s e t of 85.00 K and T c o f f s e t of 80.25 K. Additionally, XRD examinations show that optimum Dy ion substitution in the Bi-2212 system stabilizes the high superconducting phase by improving crystallinity, crystallite size, grain orientation distributions, texturing, and interlayer interactions. In contrast, excessive substitution severely deteriorates crystallographic properties. Further, SEM images reveal that the presence of optimum Dy impurity enhances the crystallinity, couplings between the adjacent layers, homogeneous surface appearance, and microstructure. Moreover, the key mechanical design features and stability of the durable tetragonal phase improve significantly for x = 0.01. As a result, the material exhibits superior mechanical properties, including a microhardness of 0.5556 GPa, fracture toughness of 0.5390 MPa.m1/2, elastic modulus of 45.5389 GPa, shear modulus of 18.2156 GPa, yield strength of 0.1852 GPa, and resilience of 0.3766 MPa under a 0.295 N load.
dc.description.sponsorshipFunding agency Bolu Abant Izzet Baysal University Research Fund Grant number 2019.09.05.1431
dc.identifier10.1088/1402-4896/adab53
dc.identifier.citationKurtul, G., Ulgen, A.T., Armağan, O., Turkoz, M.B., Erdem, Ü., & Yildirim, G. (2025). Role of dysprosium substitution on microscopy architecture, structural stability, and crack propagation mechanism in Bi-2212 engineering ceramics. Physica Scripta.
dc.identifier.doi10.1088/1402-4896/adab53
dc.identifier.issn0031-8949
dc.identifier.issn1402-4896
dc.identifier.issue2
dc.identifier.scopus2-s2.0-85216370000
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1088/1402-4896/adab53
dc.identifier.urihttps://hdl.handle.net/20.500.14619/15140
dc.identifier.volume100
dc.identifier.wosWOS:001408221000001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakScopus
dc.indekslendigikaynakWeb of Science
dc.language.isoen
dc.publisherInstitute of Physics
dc.relation.ispartofPhysica Scripta
dc.relation.ispartofseriesPhysica Scripta
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectBi-2212 ceramic
dc.subjectDy/Bi replacement
dc.subjectelectrical/superconducting features
dc.subjectmicroscopy architecture
dc.subjectslip systems
dc.titleRole of dysprosium substitution on microscopy architecture, structural stability, and crack propagation mechanism in Bi-2212 engineering ceramics
dc.typeJournal
oaire.citation.issue2
oaire.citation.volume100

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