Tetrakis[?-4-(dimethylamino)benzoato-?2O:O?]bis[(N,N-diethylnicotinamide-?N1)zinc(II)]

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dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.contributor.authorHokelek, Tuncer
dc.contributor.authorDal, Hakan
dc.contributor.authorTercan, Baris
dc.contributor.authorAybirdi, Oezguer
dc.contributor.authorNecefoglu, Hacali
dc.date.accessioned2024-09-29T16:03:15Z
dc.date.available2024-09-29T16:03:15Z
dc.date.issued2009
dc.departmentKarabük Üniversitesien_US
dc.description.abstractThe title molecule, [Zn-2(C9H10NO2)(4)(C10H14N2O)(2)], is a centrosymmetric binuclear complex, with Zn atoms [Zn center dot center dot center dot Zn ' = 2.8927 (4) angstrom] bridged by four carboxylate groups from the dimethylaminobenzoate (DMAB) ligands. The four carboxyl O atoms around the Zn atom form a distorted square-planar arrangement; the distorted square-pyramidal coordination geometry is completed by the pyridine N atom of the N,N-diethylnicotinamide (DENA) ligand. The Zn atom is displaced by 0.3326 (2) angstrom from the plane of the four O atoms, with an average Zn-O distance of 2.0416 (12) angstrom. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 5.31 (8) and 11.00 (9)degrees, while the pyridine ring is oriented at dihedral angles of 66.26 (6) and 37.88 (7)degrees with respect to the benzene rings. Weak intramolecular C-H center dot center dot center dot O and intermolecular C-H center dot center dot center dot pi interactions are present.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey [108 T657]en_US
dc.description.sponsorshipThe authors are indebted to Anadolu University and the Medicinal Plants and Medicine Research Centre of Anadolu University, Eskis, ehir, Turkey, for the use of X-ray diffractometer. This work was supported financially by the Scientific and Technological Research Council of Turkey (grant No. 108 T657).en_US
dc.identifier.doi10.1107/S1600536809047473
dc.identifier.endpageU768en_US
dc.identifier.issn2056-9890
dc.identifier.pmid21578613en_US
dc.identifier.scopus2-s2.0-72049101456en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpageM1582en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536809047473
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5991
dc.identifier.volume65en_US
dc.identifier.wosWOS:000272244600074en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Crystallographic Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleTetrakis[?-4-(dimethylamino)benzoato-?2O:O?]bis[(N,N-diethylnicotinamide-?N1)zinc(II)]en_US
dc.typeArticleen_US

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