Aquabis(isonicotinamide-?N1)bis(4-methylbenzoato)-?O;?2O,O?-cadmium(II) monohydrate

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dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.contributor.authorNecefoglu, Hacali
dc.contributor.authorCimen, Efdal
dc.contributor.authorTercan, Baris
dc.contributor.authorSuzen, Yasemin
dc.contributor.authorHokelek, Tuncer
dc.date.accessioned2024-09-29T16:03:16Z
dc.date.available2024-09-29T16:03:16Z
dc.date.issued2010
dc.departmentKarabük Üniversitesien_US
dc.description.abstractIn the crystal structure of the title compound, [Cd(C8H7O2)(2)(C6H6N2O)(2)(H2O)]center dot H2O, the Cd-II cation is coordinated by two 4-methylbenzoate (PMB) anions, two isonicotinamide (INA) ligands and one water molecule in a distorted octahedral CdN2O4 geometry. One of PMB ions acts as a bidentate ligand while the other and the two INA are monodentate ligands. An O-H center dot center dot center dot O hydrogen bond links the uncoordinated water molecule to the carboxyl groups of the complex. The dihedral angles between the carboxyl groups and the adjacent benzene rings are 10.28 (11) and 21.24 (9)degrees, while the two benzene rings and the two pyridine rings are oriented at dihedral angles of 6.90 (4) and 88.64 (4)degrees, respectively. In the crystal structure, O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds link the molecules into a supramolecular structure. A pi-pi contact between the benzene rings [centroid-centroid distance = 3.911 (1) angstrom] may further stabilize the crystal structure. Weak C-H center dot center dot center dot pi interactions involving the pyridine rings also occur in the crystal structure.en_US
dc.description.sponsorshipKafkas University [2009-FEF-03]en_US
dc.description.sponsorshipThe authors are indebted to Anadolu University and the Medicinal Plants and Medicine Research Centre of Anadolu University, Eskisehir, Turkey, for the use of X-ray diffractometer. This work was supported financially by Kafkas University Research Fund (grant No. 2009-FEF-03).en_US
dc.identifier.doi10.1107/S1600536810008366
dc.identifier.endpageU534en_US
dc.identifier.issn2056-9890
dc.identifier.pmid21580498en_US
dc.identifier.scopus2-s2.0-77951226486en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpageM392en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536810008366
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5996
dc.identifier.volume66en_US
dc.identifier.wosWOS:000276190700039en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Crystallographic Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleAquabis(isonicotinamide-?N1)bis(4-methylbenzoato)-?O;?2O,O?-cadmium(II) monohydrateen_US
dc.typeArticleen_US

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