Diaquabis(N,N-diethylnicotinamide-?N1)bis(4-methylbenzoato-?O)cobalt(II)

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dc.authoridERMIS, EMEL/0000-0003-3052-4123
dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.contributor.authorNecefoglu, Hacali
dc.contributor.authorCimen, Efdal
dc.contributor.authorTercan, Baris
dc.contributor.authorErmis, Emel
dc.contributor.authorHokelek, Tuncer
dc.date.accessioned2024-09-29T16:03:17Z
dc.date.available2024-09-29T16:03:17Z
dc.date.issued2010
dc.departmentKarabük Üniversitesien_US
dc.description.abstractIn the centrosymmetric mononuclear title complex, [Co(C8H7O2)(2)(C10H14N2O)(2)(H2O)(2)], the Co-II ion is located on an inversion center. The asymmetric unit contains one 4-methylbenzoate (PMB)anion, one N,N-diethylnicotinamide (DENA)ligand and one coordinated water molecule. The four O atoms in the equatorial plane around the Co-II ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the DENA ligands in the axial positions. The dihedral angle between the carboxylate group and the attached benzene ring is 3.73 (14)degrees, while the pyridine and benzene rings are oriented at a dihedral angle of 77.28 (6)degrees. In the crystal structure, intermolecular O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds link the molecules into a twodimensional network parallel to (001). The structure is further stabilized by pi-pi contacts between the pyridine rings [centroid-centroid distance = 3.544 (1)angstrom] and weak C-H center dot center dot center dot pi interactions involving the benzene ring.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey [108 T657]en_US
dc.description.sponsorshipThe authors are indebted to Anadolu University and the Medicinal Plants and Medicine Research Centre of Anadolu University, Eskis, ehir, Turkey, for the use of X-ray diffractometer. This work was supported financially by the Scientific and Technological Research Council of Turkey (grant No. 108 T657).en_US
dc.identifier.doi10.1107/S1600536810013954
dc.identifier.endpageU814en_US
dc.identifier.issn1600-5368
dc.identifier.pmid21579040en_US
dc.identifier.scopus2-s2.0-77952055342en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpageM556en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536810013954
dc.identifier.urihttps://hdl.handle.net/20.500.14619/6001
dc.identifier.volume66en_US
dc.identifier.wosWOS:000277240600060en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherWiley-Blackwellen_US
dc.relation.ispartofActa Crystallographica Section E-Structure Reports Onlineen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleDiaquabis(N,N-diethylnicotinamide-?N1)bis(4-methylbenzoato-?O)cobalt(II)en_US
dc.typeArticleen_US

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