Investigation of [MSalen/salophen] (M = Cr3+, Fe3+ or Co3+) capped dinuclear complexes of two novel tetraoxocalix[2](m-hydroxymethyl)arene[2]triazine compounds

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dc.authoridUYSAL, Saban/0000-0003-1061-6143
dc.contributor.authorAouled, Idriss Mahamoud
dc.contributor.authorUysal, Saban
dc.date.accessioned2024-09-29T16:01:14Z
dc.date.available2024-09-29T16:01:14Z
dc.date.issued2021
dc.departmentKarabük Üniversitesien_US
dc.description.abstractIn this work, (3,5-bis((4,6-dichloro-1,3,5-triazine-2-yl)oxy)phenyl)methanol was obtained by reacting cyanuric chloride with 3,5-dihydroxybenzyl alcohol at 0 degrees C. Then, s-triazine bridged calixarene codded as L1 was obtained by reacting the compounds with 3,5-dihydroxybenzyl alcohol. Targed ligands, which we code as L2 and L3, were obtained from the reaction of the L1 coded compound with 4-aminobenzoic acid or 4-hydroxybenzoic acid, respectively. [MSalen/Saloph] capped s-triazine bridged calixarene complexes were obtained from the reaction of the L2 or L3 codded ligand and the [(MSalen/Saloph)(2)O] (M = Cr3+, Fe3+, Co3+) starting complexes in 1,4-dioxane media. The ligands and complexes were characterized by using H-1-NMR, FT-IR spectroscopy, UV-Vis spectroscopies, magnetic susceptibility, TGA-DTA and elemental analysis techniques. Metal contents of the complexes were determined by using ICP-AES spectroscopy. Calixarenes can be used in many areas such as chiral phase transfer catalyst, recognition of enantiomers, stationary phase in chromatography, recovery of heavy and precious metals molecules or ions from environmental wastes.en_US
dc.description.sponsorshipKarabuk University Scientific Research Projects Coordinatorship [FYL-2020-2189]en_US
dc.description.sponsorshipWe acknowledge that this study was financially supported by the Karabuk University Scientific Research Projects Coordinatorship (Project No: FYL-2020-2189).en_US
dc.identifier.doi10.1080/00397911.2021.1988107
dc.identifier.endpage3655en_US
dc.identifier.issn0039-7911
dc.identifier.issn1532-2432
dc.identifier.issue23en_US
dc.identifier.scopus2-s2.0-85116852963en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage3642en_US
dc.identifier.urihttps://doi.org/10.1080/00397911.2021.1988107
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5605
dc.identifier.volume51en_US
dc.identifier.wosWOS:000705132500001en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherTaylor & Francis Incen_US
dc.relation.ispartofSynthetic Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCalix[2]arene[2]triazinesen_US
dc.subjectsalenen_US
dc.subjectsalophen_US
dc.subjects-triazine bridged calixareneen_US
dc.subjects-triazine bridged calixarene complexesen_US
dc.titleInvestigation of [MSalen/salophen] (M = Cr3+, Fe3+ or Co3+) capped dinuclear complexes of two novel tetraoxocalix[2](m-hydroxymethyl)arene[2]triazine compoundsen_US
dc.typeArticleen_US

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