Diaquabis(4-bromobenzoato-?O)bis(nicotinamide-?N1)copper(II)

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dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.authoridOzturkkan, Fureya Elif/0000-0001-6376-4161
dc.contributor.authorNecefoglu, Hacali
dc.contributor.authorOzbek, Fureya Elif
dc.contributor.authorOzturk, Vijdan
dc.contributor.authorTercan, Baris
dc.contributor.authorHokelek, Tuncer
dc.date.accessioned2024-09-29T16:03:22Z
dc.date.available2024-09-29T16:03:22Z
dc.date.issued2011
dc.departmentKarabük Üniversitesien_US
dc.description.abstractThe asymmetric unit of the title mononuclear Cu-II complex, [Cu(C7H4BrO2)(2)(C6H6N2O)(2)(H2O)(2)], contains one half-molecule, the Cu-II atom being located on an inversion center. The unit cell contains two nicotinamide (NA), two 4-bromo-benzoate (PBB) ligands and two coordinated water molecules. The four O atoms in the equatorial plane around the Cu-II ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 22.17 (16)degrees, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 82.80 (6)degrees. In the crystal, N-H center dot center dot center dot O, O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds link the molecules into a three-dimensional network. A weak C-H center dot center dot center dot pi interaction is also observed.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey [108 T657]en_US
dc.description.sponsorshipThe authors are indebted to Anadolu University and the Medicinal Plants and Medicine Research Centre of Anadolu University, Eskisehir, Turkey, for the use of X-ray diffractometer. This work was supported financially by the Scientific and Technological Research Council of Turkey (grant No. 108 T657).en_US
dc.identifier.doi10.1107/S1600536811021696
dc.identifier.endpageU787en_US
dc.identifier.issn1600-5368
dc.identifier.pmid21836889en_US
dc.identifier.scopus2-s2.0-79960055334en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpageM900en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536811021696
dc.identifier.urihttps://hdl.handle.net/20.500.14619/6034
dc.identifier.volume67en_US
dc.identifier.wosWOS:000294663000058en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherWiley-Blackwellen_US
dc.relation.ispartofActa Crystallographica Section E-Structure Reports Onlineen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleDiaquabis(4-bromobenzoato-?O)bis(nicotinamide-?N1)copper(II)en_US
dc.typeArticleen_US

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