Bis(4-methoxybenzoato)-?2O,O?;?O-bis(nicotinamide-?N1)zinc(II)

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dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.contributor.authorHoekelek, Tuncer
dc.contributor.authorSaka, Guener
dc.contributor.authorTercan, Baris
dc.contributor.authorTenlik, Erdinc
dc.contributor.authorNecefoglu, Hacali
dc.date.accessioned2024-09-29T16:03:19Z
dc.date.available2024-09-29T16:03:19Z
dc.date.issued2010
dc.departmentKarabük Üniversitesien_US
dc.description.abstractThe asymmetric unit of the title complex, [Zn(C8H7O3)(2)-(C6H6N2O)(2)], contains three crystallographically independent molecules with similar configurations. The Zn-II cation is coordinated by two N atoms of two nicotinamide ligands and three O atoms from two 4-methoxybenzoate anions in a distorted trigonal-bipyramidal geometry. In each independent molecule, one Zn-O bond distance [2.5181 (12), 2.5931 (12) and 2.4085 (12) angstrom for the three molecules] is significantly longer than the other two. In the crystal structure, extensive N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonding links the molecules into a three-dimensional network. pi-pi contacts between the pyridine rings and between the pyridine and benzene rings [centroid-centroid distances = 3.7655 (9) and 3.8453 (10) angstrom, respectively] further stabilize the crystal structure.en_US
dc.description.sponsorshipKafkas University [2009-FEF-03]en_US
dc.description.sponsorshipThe authors are indebted to Anadolu University and the Medicinal Plants and Medicine Research Centre of Anadolu University, Eskisehir, Turkey, for the use of X-ray diffractometer. This work was supported financially by Kafkas University Research Fund (grant No. 2009-FEF-03).en_US
dc.identifier.doi10.1107/S1600536810032885
dc.identifier.endpageU871en_US
dc.identifier.issn1600-5368
dc.identifier.pmid21588535en_US
dc.identifier.scopus2-s2.0-77956300938en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpageM1135en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536810032885
dc.identifier.urihttps://hdl.handle.net/20.500.14619/6017
dc.identifier.volume66en_US
dc.identifier.wosWOS:000281447800066en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherWiley-Blackwellen_US
dc.relation.ispartofActa Crystallographica Section E-Structure Reports Onlineen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectDihydrateen_US
dc.titleBis(4-methoxybenzoato)-?2O,O?;?O-bis(nicotinamide-?N1)zinc(II)en_US
dc.typeArticleen_US

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