Tetraaquabis(isonicotinamide-?N1)cobalt(II) bis(4-formylbenzoate) dihydrate

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dc.authoridSERTCELIK, MUSTAFA/0000-0001-7919-7907
dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.contributor.authorHokelek, Tuncer
dc.contributor.authorYilmaz, Filiz
dc.contributor.authorTercan, Baris
dc.contributor.authorSertcelik, Mustafa
dc.contributor.authorNecefoglu, Hacali
dc.date.accessioned2024-09-29T16:03:15Z
dc.date.available2024-09-29T16:03:15Z
dc.date.issued2009
dc.departmentKarabük Üniversitesien_US
dc.description.abstractThe asymmetric unit of the crystal structure of the title complex, [Co(C6H6N2O)(2)(H2O)(4)](C8H5O3)(2)center dot 2H(2)O, contains one-half of the complex cation with the Co-II ion located on an inversion center, a 4-formylbenzoate (FB) counter-anion and an uncoordinated water molecule. The four O atoms in the equatorial plane around the Co-II ion form a slightly distorted square-planar arrangement with an average Co-O bond length of 2.086 angstrom; the slightly distorted octahedral coordination is completed by the two N atoms of the isonicotinamide (INA) ligands at a slightly longer distance [2.1603 (14) angstrom] in the axial positions. The dihedral angle between the carboxylate group and the attached benzene ring is 5.93 (13)degrees, while the pyridine and benzene rings are oriented at a dihedral angle of 3.09 (6)degrees. In the crystal structure, O-H center dot center dot center dot O, N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds link the molecules into a three-dimensional network. pi-pi Contacts between the benzene and pyridine rings [centroid-centroid distance = 3.758 (1) angstrom] may further stabilize the crystal structure.en_US
dc.description.sponsorshipKafkas University Research Fund [2009-FEF-03]en_US
dc.description.sponsorshipThe authors are indebted to Anadolu University and the Medicinal Plants and Medicine Research Centre of Anadolu University, Eskis, ehir, Turkey, for the use of the X-ray diffractometer. This work was supported financially by Kafkas University Research Fund ( grant No. 2009-FEF-03).en_US
dc.identifier.doi10.1107/S1600536809033200
dc.identifier.endpageU1034en_US
dc.identifier.issn2056-9890
dc.identifier.pmid21577469en_US
dc.identifier.scopus2-s2.0-70249083090en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpageM1130en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536809033200
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5985
dc.identifier.volume65en_US
dc.identifier.wosWOS:000269523400084en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Structure Reports Onlineen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleTetraaquabis(isonicotinamide-?N1)cobalt(II) bis(4-formylbenzoate) dihydrateen_US
dc.typeArticleen_US

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