Cadmium(II) coordination polymers based on 3,3'-azobis(pyridine) and some aliphatic dicarboxylates: Hydrothermal synthesis, crystal structures, thermal stabilities and photoluminescence

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dc.authoridArslan Bicer, Figen/0000-0002-4024-8233
dc.contributor.authorBicer, Figen Arslan
dc.date.accessioned2024-09-29T16:00:33Z
dc.date.available2024-09-29T16:00:33Z
dc.date.issued2023
dc.departmentKarabük Üniversitesien_US
dc.description.abstractThree new Cd(II) coordination polymers (CPs), namely, [Cd-2(mu-phsuc)(2)(mu-abpy)(2)(H2O)(2)](n) (1), {[Cd(mu(3)-glu) (mu-abpy)]center dot 3H(2)O}(n) (2) and {[Cd(mu-dmglu)(mu-abpy)(H2O)]center dot H2O}(n) (3), were synthesized by hydrothermally from 3,3'-azobis(pyridine) (abpy) using three different aliphatic dicarboxylic acids [phenyl succinic acid (phsucH(2)), glutaric acid (gluH(2)) and 3,3'-dimethyl glutaric acid (dmgluH(2))]. The structures of 1-3 were characterized by elemental analysis, infrared spectroscopy (IR), single crystal X-ray and powder X-ray diffraction (PXRD) techniques. X-ray diffraction studies have revealed that 1-3 crystallize in the monoclinic system, P21/n space group (1) and C2/c space group (2, 3). 1 and 2 show 3D structure, whereas 3 exhibits an interesting 2-fold interpenetrating 2D structure. The thermal stabilities of the CPs were studied by thermal analysis (TG/DTA) techniques. In addition, the photoluminescence properties of the CPs have been investigated.en_US
dc.identifier.doi10.1016/j.poly.2023.116579
dc.identifier.issn0277-5387
dc.identifier.issn1873-3719
dc.identifier.scopus2-s2.0-85167965535en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1016/j.poly.2023.116579
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5220
dc.identifier.volume244en_US
dc.identifier.wosWOS:001067998900001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofPolyhedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCadmium(II) complexesen_US
dc.subjectPhenyl succinic aciden_US
dc.subjectGlutaric aciden_US
dc.subject3,3'-dimethylglutaric aciden_US
dc.subject3,3'-azobis(pyridine) complexesen_US
dc.titleCadmium(II) coordination polymers based on 3,3'-azobis(pyridine) and some aliphatic dicarboxylates: Hydrothermal synthesis, crystal structures, thermal stabilities and photoluminescenceen_US
dc.typeArticleen_US

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