Deconstruction of lignocellulosic biomass with hydrated cerium (III) chloride in water and ethanol

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dc.authoridRagauskas, Arthur/0000-0002-3536-554X
dc.authoridTekin, Kubilay/0000-0002-9373-3208
dc.authoridALPER, Koray/0000-0001-6845-2087
dc.contributor.authorAkalin, Mehmet K.
dc.contributor.authorDas, Parthapratim
dc.contributor.authorAlper, Koray
dc.contributor.authorTekin, Kubilay
dc.contributor.authorRagauskas, Arthur J.
dc.contributor.authorKaragoz, Selhan
dc.date.accessioned2024-09-29T15:54:56Z
dc.date.available2024-09-29T15:54:56Z
dc.date.issued2017
dc.departmentKarabük Üniversitesien_US
dc.description.abstractLignocellulosic biomass was decomposed to produce crude bio-oil in water and ethanol using hydrated cerium (III) chloride as a catalyst. Use of the catalyst affected not only the yield of crude bio-oil but also the composition of bio-crude for both water and ethanol. The catalyst had a detrimental effect on the crude bio-oil yields obtained from water processing for all runs. However, in ethanol, use of the catalyst improved the crude bio-oil yields in all tested runs. The solid residue yields decreased with the catalyst use in the runs with water but increased in all studies with ethanol, except those with the shortest tested residence time of 10 min. The highest crude bio-oil yield of 48.2 wt% was obtained at 300 degrees C using 5 mmol of hydrated cerium (III) chloride at a residence time of 90 min in ethanol. The heating values of the crude bio-oils increased with the catalyst use for both water and ethanol processing. The highest heating value of 33.3 MJ kg(-1) was obtained with hydrated cerium (III) chloride at 300 degrees C and a residence time of 120 min.en_US
dc.description.sponsorshipKarabuk University [KBU-BAP-16/2-DS-016]en_US
dc.description.sponsorshipThe authors gratefully thank Karabuk University for the financial support (KBU-BAP-16/2-DS-016).en_US
dc.identifier.doi10.1016/j.apcata.2017.08.010
dc.identifier.endpage78en_US
dc.identifier.issn0926-860X
dc.identifier.issn1873-3875
dc.identifier.scopus2-s2.0-85027528467en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage67en_US
dc.identifier.urihttps://doi.org/10.1016/j.apcata.2017.08.010
dc.identifier.urihttps://hdl.handle.net/20.500.14619/4374
dc.identifier.volume546en_US
dc.identifier.wosWOS:000412254800009en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Bven_US
dc.relation.ispartofApplied Catalysis A-Generalen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectWateren_US
dc.subjectEthanolen_US
dc.subjectBiomassen_US
dc.subjectConversionen_US
dc.subjectLewis acidsen_US
dc.titleDeconstruction of lignocellulosic biomass with hydrated cerium (III) chloride in water and ethanolen_US
dc.typeArticleen_US

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