Diaquabis(N,N-diethylnicotinamide-?N1)bis[4-(dimethylamino)benzoato-?O]cobalt(II)

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dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.contributor.authorHokelek, Tuncer
dc.contributor.authorDal, Hakan
dc.contributor.authorTercan, Baris
dc.contributor.authorAybirdi, Oezguer
dc.contributor.authorNecefoglu, Hacali
dc.date.accessioned2024-09-29T16:03:15Z
dc.date.available2024-09-29T16:03:15Z
dc.date.issued2009
dc.departmentKarabük Üniversitesien_US
dc.description.abstractThe title Co-II complex, [Co(C9H10NO2)(2)(C10H14N2O)(2)-(H2O)(2)], is centrosymmetric. It contains two dimethylaminobenzoate (DMAB) and two diethylnicotinamide (DENA) ligands and two water molecules, all of them being monodentate. The four O atoms in the equatorial plane around the Co atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of DENA ligands with the Co-N distance of 2.1519 (11) angstrom in the axial positions. The Co atom is displaced out of the least-squares plane of the carboxylate group by -0.781 (1) angstrom. The dihedral angle between the carboxylate group and the adjacent benzene ring is 5.05 (7)degrees, while the pyridine and benzene rings are oriented at a dihedral angle of 71.48 (5)degrees. In the crystal structure, intermolecular O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds link the molecules into a three-dimensional network. Two weak C-H center dot center dot center dot pi interactions are also present.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey [108 T657]en_US
dc.description.sponsorshipThe authors are indebted to Anadolu University and the Medicinal Plants and Medicine Research Centre of Anadolu University, Eskisehir, Turkey, for the use of the X-ray diffractometer. This work was supported financially by the Scientific and Technological Research Council of Turkey (grant No. 108 T657).en_US
dc.identifier.doi10.1107/S1600536809030980
dc.identifier.endpageU398en_US
dc.identifier.issn2056-9890
dc.identifier.pmid21577412en_US
dc.identifier.scopus2-s2.0-70249147254en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpageM1051en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536809030980
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5983
dc.identifier.volume65en_US
dc.identifier.wosWOS:000269523400027en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Structure Reports Onlineen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectCrystalen_US
dc.titleDiaquabis(N,N-diethylnicotinamide-?N1)bis[4-(dimethylamino)benzoato-?O]cobalt(II)en_US
dc.typeArticleen_US

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