Synthesis, Crystal Structures and Spectrothermal Characterization of a Heptacoordinated Dimeric Salicylato Cadmium(H) Complex with 2,2?-Azobispyridine (abpy), (?-abpy)[Cd(HsaI)2(abpy)]2

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dc.authoridArslan Bicer, Figen/0000-0002-4024-8233
dc.contributor.authorArslan, Figen
dc.contributor.authorOlmez, Halis
dc.contributor.authorOdabasoglu, Mustafa
dc.contributor.authorBuyukgungor, Orhan
dc.date.accessioned2024-09-29T15:50:51Z
dc.date.available2024-09-29T15:50:51Z
dc.date.issued2010
dc.departmentKarabük Üniversitesien_US
dc.description.abstractmu-2,2'-Azobispyridinebis[2,2'-azobispyridinesalicylato(O)-salicylato(O,O') cadmium(II), (mu-abpY)[Cd(HsaI)(2)(abpy)](2) (I) was synthesized and characterized by IR and UV/Vis spectroscopy, thermal analysis, and X-ray diffraction techniques. Two abpy ligands and two salicylato ligands coordinate to the Cd2+ ion in a monocapped trigonal-prismatic arrangement. The capping atom is the N3 atom. One of the two abpy ligands behaves as a s-frame bridging ligand and adopts a s-cis/E/s-cis conformation, whereas the other one adopts as a s-cis/E/s-trans conformation. One of the two salicylato ligands acts as a monodentate ligand, which coordinates with the carboxylate oxygen atom, whereas the other one adopts bidentate coordination through two carboxylate oxygen atoms. The hydroxy groups of salicylato ligands, which coordinate in a monodentate fashion, are disordered over two positions, with occupancies of 0.52 for group A and 0.48 for group B. The decomposition reaction takes place in the temperature range 20-1000 degrees C under nitrogen. Thermal decomposition of the title complex proceeds in two stages.en_US
dc.identifier.doi10.1002/zaac.200900333
dc.identifier.endpage1644en_US
dc.identifier.issn0044-2313
dc.identifier.issn1521-3749
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-77955444391en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage1641en_US
dc.identifier.urihttps://doi.org/10.1002/zaac.200900333
dc.identifier.urihttps://hdl.handle.net/20.500.14619/3757
dc.identifier.volume636en_US
dc.identifier.wosWOS:000280659500038en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofZeitschrift Fur Anorganische Und Allgemeine Chemieen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCadmiumen_US
dc.subjectAzobispyridinesen_US
dc.subjectThermal analysisen_US
dc.subjectChelatesen_US
dc.subjectN ligandsen_US
dc.titleSynthesis, Crystal Structures and Spectrothermal Characterization of a Heptacoordinated Dimeric Salicylato Cadmium(H) Complex with 2,2?-Azobispyridine (abpy), (?-abpy)[Cd(HsaI)2(abpy)]2en_US
dc.typeArticleen_US

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