Diaquabis(4-methylbenzoato-?O)bis(nicotinamide-?N1)nickel(II)

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dc.authoridERMIS, EMEL/0000-0003-3052-4123
dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.contributor.authorNecefoglu, Hacali
dc.contributor.authorCimen, Efdal
dc.contributor.authorTercan, Baris
dc.contributor.authorErmis, Emel
dc.contributor.authorHokelek, Tuncer
dc.date.accessioned2024-09-29T16:03:16Z
dc.date.available2024-09-29T16:03:16Z
dc.date.issued2010
dc.departmentKarabük Üniversitesien_US
dc.description.abstractThe title Ni-II complex, [Ni(C8H7O2)(2)(C6H6N2O)(2)(H2O)(2)], is centrosymmetric with the Ni atom located on an inversion center. The molecule contains two 4-methylbenzoate (PMB) and two nicotinamide (NA)ligands and two coordinated water molecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Ni atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 26.15 (10)degrees, while the pyridine and benzene rings are oriented at a dihedral angle of 87.81 (4)degrees. In the crystal structure, intermolecular O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds link the molecules into a three-dimensional network. The pi-pi contact between the benzene rings [centroid-centroid distance = 3.896 (1) angstrom] may further stabilize the crystal structure. A weak C-H center dot center dot center dot pi interaction involving the pyridine ring also occurs.en_US
dc.identifier.doi10.1107/S1600536810007385
dc.identifier.endpageU277en_US
dc.identifier.issn2056-9890
dc.identifier.pmid21580476en_US
dc.identifier.scopus2-s2.0-77951229581en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpageM361en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536810007385
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5995
dc.identifier.volume66en_US
dc.identifier.wosWOS:000276190700017en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Crystallographic Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleDiaquabis(4-methylbenzoato-?O)bis(nicotinamide-?N1)nickel(II)en_US
dc.typeArticleen_US

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