Co-hydrothermal Liquefaction of Lignocellulosic Biomass with Kukersite Oil Shale

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dc.authoridDURUKAN, ILKNUR/0000-0002-7200-5789
dc.authoridTekin, Kubilay/0000-0002-9373-3208
dc.authoridKaragoz, Selhan/0000-0003-4794-6525
dc.authoridKim, Young-Min/0000-0003-2639-3052
dc.authoridSiddiqui, Muhammad Zain/0000-0003-3332-8136
dc.authoridALPER, Koray/0000-0001-6845-2087
dc.contributor.authorAkalin, Ece
dc.contributor.authorKim, Young-Min
dc.contributor.authorAlper, Koray
dc.contributor.authorOja, Vahur
dc.contributor.authorTekin, Kubilay
dc.contributor.authorDurukan, Ilknur
dc.contributor.authorSiddiqui, Muhammad Zain
dc.date.accessioned2024-09-29T16:00:59Z
dc.date.available2024-09-29T16:00:59Z
dc.date.issued2019
dc.departmentKarabük Üniversitesien_US
dc.description.abstractThe co-hydrothermal liquefaction of black pine wood (BPW) with Kukersite oil shale (KOS) at different blend ratios of BPW/KOS (1:1, 1:2, and 2:1) was conducted at 300 degrees C for 30 min. No synergistic effects on oil yields from the co-hydrothermal processing have been observed. However, when the methanol was substituted with hot compressed water as the solvent, positive synergistic effects on the oil yields were observed for all blend ratios, but the heating values of the oils from hydrothermal processing were higher than those from supercritical methanol processing under identical conditions. Co-hydrothermal liquefaction of BPW with KOS produced oils with less oxygen than those from co-supercritical methanol processing of BPW with KOS under identical conditions. The highest heating value from co-processing was 30.22 MJ/kg, which was obtained from the co-hydrothermal liquefaction of BPW with KOS at a blend ratio of 1:2. Oils from the co-hydrothermal liquefaction of BPW with KOS contained phenols, acids, ketones, and aldehydes. Guaiacol was the primary compound detected in the oils from co-hydrothermal processing. The relative yield of this compound was highest at a blend ratio of 1:2 (BPW/KOS). The prominent compounds in oils from the co-supercritical methanol processing were esters and phenols.en_US
dc.description.sponsorshipKarabuk University and Frontier Laboratories Ltd. (Japan)en_US
dc.description.sponsorshipThis project was supported by Karabuk University and Frontier Laboratories Ltd. (Japan). Special thanks go to Atsushi Watanabe from Frontier Laboratories Ltd. for useful discussions and suggestions concerning Tandem Py-GC-MS experiments.en_US
dc.identifier.doi10.1021/acs.energyfuels.9b01473
dc.identifier.endpage7435en_US
dc.identifier.issn0887-0624
dc.identifier.issn1520-5029
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-85071696140en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage7424en_US
dc.identifier.urihttps://doi.org/10.1021/acs.energyfuels.9b01473
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5470
dc.identifier.volume33en_US
dc.identifier.wosWOS:000481569100056en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherAmer Chemical Socen_US
dc.relation.ispartofEnergy & Fuelsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSupercritical Methanolen_US
dc.subjectChemical Conversionen_US
dc.subjectEstonian Kukersiteen_US
dc.subjectBio-Oilen_US
dc.subjectPyrolysisen_US
dc.subjectSynergyen_US
dc.subjectWateren_US
dc.subjectMicroalgaeen_US
dc.subjectResourcesen_US
dc.subjectProductsen_US
dc.titleCo-hydrothermal Liquefaction of Lignocellulosic Biomass with Kukersite Oil Shaleen_US
dc.typeArticleen_US

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