Diaquabis(2-chlorobenzoato-?O)bis(nicotinamide-?N1)nickel(II)

Basit Öğe Kaydı
dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.authoridOzturkkan, Fureya Elif/0000-0001-6376-4161
dc.contributor.authorHoekelek, Tuncer
dc.contributor.authorDal, Hakan
dc.contributor.authorTercan, Baris
dc.contributor.authorOezbek, F. Elif
dc.contributor.authorNecefoglu, Hacali
dc.date.accessioned2024-09-29T16:03:13Z
dc.date.available2024-09-29T16:03:13Z
dc.date.issued2009
dc.departmentKarabük Üniversitesien_US
dc.description.abstractThe title Ni-II complex, [Ni(C7H4ClO2)(2)(C6H6N2O)(2)(H2O)(2)], is centrosymmetric with the Ni atom located on an inversion centre. The molecule contains two 2-chlorobenzoate (CB) and two nicotinamide (NA) ligands and two water molecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Ni atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 29.48 (16)degrees, while the pyridine and benzene rings are oriented at a dihedral angle of 83.16 (5)degrees. In the crystal structure, O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds link the molecules into infinite chains. pi-pi Contacts between the benzene and pyridine rings [centroid-centroid distance = 3.952 (1) angstrom] may further stabilize the crystal structure. There is also a C-H center dot center dot center dot pi interaction.en_US
dc.identifier.doi10.1107/S1600536809011209
dc.identifier.endpageU1104en_US
dc.identifier.issn2056-9890
dc.identifier.pmid21582397en_US
dc.identifier.scopus2-s2.0-64149110733en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpageM466en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536809011209
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5966
dc.identifier.volume65en_US
dc.identifier.wosWOS:000264798500092en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Structure Reports Onlineen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectMolecular-Structureen_US
dc.subjectCrystalen_US
dc.titleDiaquabis(2-chlorobenzoato-?O)bis(nicotinamide-?N1)nickel(II)en_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
PubMed İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu