Diaquabis(N,N-diethylnicotinamide-?N1)bis[4-(dimethylamino)benzoato-?O]nickel(II)

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dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.contributor.authorHoekelek, Tuncer
dc.contributor.authorSuezen, Yasemin
dc.contributor.authorTercan, Baris
dc.contributor.authorAybirdi, Oezguer
dc.contributor.authorNecefoglu, Hacali
dc.date.accessioned2024-09-29T16:03:15Z
dc.date.available2024-09-29T16:03:15Z
dc.date.issued2009
dc.departmentKarabük Üniversitesien_US
dc.description.abstractThe centrosymmetric title Ni-II complex, [Ni(C9H10NO2)(2)-(C10H14N2O)(2)(H2O)(2)], contains two dimethylaminobenzoate (DMAB), two diethylnicotinamide (DENA) ligands and two water molecules, all of them monodentate. The four O atoms in the equatorial plane around the Ni-II atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the DENA ligands in axial positions. The Ni-II atom is displaced by 0.681 (1) angstrom out of the least-squares plane of the carboxylate group. The dihedral angle between the carboxylate group and the adjacent benzene ring is 5.61 (7)degrees, while the pyridine and benzene rings are oriented at a dihedral angle of 73.20 (4)degrees. An intramolecular O-H center dot center dot center dot O hydrogen bond results in the formation of a six-membered ring with a twisted conformation. In the crystal structure, intermolecular O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds link molecules into a three-dimensional network. Two weak C-H center dot center dot center dot pi interactions are also present.en_US
dc.identifier.doi10.1107/S1600536809030098
dc.identifier.endpageU1746en_US
dc.identifier.issn2056-9890
dc.identifier.pmid21583312en_US
dc.identifier.scopus2-s2.0-68749099611en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpageM1015en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536809030098
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5982
dc.identifier.volume65en_US
dc.identifier.wosWOS:000268510800143en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Crystallographic Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleDiaquabis(N,N-diethylnicotinamide-?N1)bis[4-(dimethylamino)benzoato-?O]nickel(II)en_US
dc.typeArticleen_US

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