Development of modulation, pairing mechanism, and slip system with optimum vanadium substitution at Bi-sites in Bi-2212 ceramic structure

Basit Öğe Kaydı
dc.authoridTURKOZ, MUSTAFA BURAK/0000-0002-4127-7650
dc.authoridTURGAY, Tahsin/0000-0003-0304-1097
dc.authoridUlgen, Asaf Tolga/0000-0002-7112-5607
dc.authoridErdem, Umit/0000-0002-0480-8176
dc.contributor.authorUlgen, Asaf Tolga
dc.contributor.authorOkur, Semih
dc.contributor.authorErdem, Umit
dc.contributor.authorTerzioglu, Cabir
dc.contributor.authorTurgay, Tahsin
dc.contributor.authorTurkoz, Mustafa Burak
dc.contributor.authorYildirim, Gurcan
dc.date.accessioned2024-09-29T15:57:51Z
dc.date.available2024-09-29T15:57:51Z
dc.date.issued2023
dc.departmentKarabük Üniversitesien_US
dc.description.abstractPresent study focuses extensively on the change in electrical, superconducting and microhardness parameters with partial substitution of trivalent V+3 impurities replacing Bi+3 ions in Bi-2212 ceramic compound with the aid of dc electrical resistivity and microhardness test measurements. Experimental findings, calculation results, and phenomenological discussions provide that the optimum vanadium substitution level is found to be x = 0.01 in the Bi2.0-xVxSr2.0Ca1.1Cu2.0Oy (Bi-2212) ceramic system for the highest conductivity, crystallinity quality, superconducting, and mechanical performance features depending on the decreased microscopic structural problems. All the findings are wholly verified by scanning electron microscopy (SEM) and X-Ray diffraction (XRD) analyses. The dc electrical measurements indicate that the optimum vanadium ions support the pairing mechanism for the formation of new polaronic states in the clusters of microdomains, and hence expand superconducting energy gap due to the enhancement of amplitude part of pair wave function in the spin-density wave systems. The excess vanadium content degrades all the basic thermodynamics and quantum mechanical quantities mentioned due to the stress-induced phase transformation. Numerically, the Bi-2212 advanced ceramic matrix prepared by the optimum vanadium impurity is noticed to present the smallest residual resistivity value of 0.08 m & omega; cm, room temperature resistivity value of 8.84 m & omega; cm, and broadening degree of 0.36 K. Similarly, the ceramic material is found to possess the highest residual resistivity ratio of 3.05, carrier concen-tration number of 0.153041, critical transition offset and onset value of 84.66 K and 85.02 K, respectively. Besides, the microhardness findings reveal that the same compound with the least sensitivity to the applied test loads exhibits the largest Hv value of 4.799 GPa, Young's moduli of 393.303 GPa, yield strength of (0.969 GPa), and elastic stiffness coefficient of 15.5574 (GPa)7/4 under the applied test load of 0.245 N. The XRD in-vestigations show that the presence of optimum vanadium impurity supports the formation of a high super-conducting phase, c-axis length, and average crystallite size. All the findings are morphologically confirmed by the SEM images. It is found that the crystallographically best crystallinity quality and view of surface morphology is observed for the optimum vanadium substitution level. All in all, new higher properties for the conductivity, crystallinity quality, surface morphology, superconducting, and microhardness parameters based on the optimum vanadium replacement encourage the Bi-2212 crystal system to use in much more application places.en_US
dc.identifier.doi10.1016/j.matchemphys.2023.128171
dc.identifier.issn0254-0584
dc.identifier.issn1879-3312
dc.identifier.scopus2-s2.0-85166006832en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.urihttps://doi.org/10.1016/j.matchemphys.2023.128171
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5042
dc.identifier.volume307en_US
dc.identifier.wosWOS:001046841300001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofMaterials Chemistry and Physicsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBi-2212 advanced ceramicen_US
dc.subjectVen_US
dc.subjectBi replacementen_US
dc.subjectPairing mechanismen_US
dc.subjectHybridizationen_US
dc.subjectModulationen_US
dc.titleDevelopment of modulation, pairing mechanism, and slip system with optimum vanadium substitution at Bi-sites in Bi-2212 ceramic structureen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu