Tetrakis[?-4-(diethylamino)benzoato-?2O:O?]bis[(N,N-diethylnicotinamide-?N1)cobalt(II)]

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dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.authoridSAGLAM, Ertugrul Gazi/0000-0002-7719-3934
dc.contributor.authorHokelek, Tuncer
dc.contributor.authorSaglam, Ertugrul Gazi
dc.contributor.authorTercan, Baris
dc.contributor.authorAybirdi, Ozgur
dc.contributor.authorNecefoglu, Hacali
dc.date.accessioned2024-09-29T16:03:19Z
dc.date.available2024-09-29T16:03:19Z
dc.date.issued2011
dc.departmentKarabük Üniversitesien_US
dc.description.abstractIn the centrosymmetric binuclear title complex, [Co-2(C11H14-NO2)(4)(C10H14N2O)(2)], the two Co-II cations [Co center dot center dot center dot Co = 2.6199 (5) angstrom] are bridged by four 4-(diethylamino)benzoate (DEAB) anions. The four nearest O atoms around each Co-II ion form a distorted square-planar arrangement, the distorted square-pyramidal coordination geometry being completed by the pyridine N atom of an N, N-diethylnicotinamide (DENA) ligand. The dihedral angle between the benzene ring and the carboxylate group is 7.06 (11)degrees in one of the independent DEAB ligands and 4.42 (9)degrees in the other. The benzene rings of the two independent DEAB ligands are oriented at a dihedral angle of 86.35 (8)degrees. The pyridine ring is oriented at dihedral angles of 31.43 (6) and 57.92 (7)degrees with respect to the two benzene rings. In the crystal, weak intermolecular C-H center dot center dot center dot O interactions link the molecules into a three-dimensional network. Weak C-H center dot center dot center dot pi interactions are also present in the crystal structure.en_US
dc.identifier.doi10.1107/S160053681005004X
dc.identifier.endpageU404en_US
dc.identifier.issn2056-9890
dc.identifier.pmid21522552en_US
dc.identifier.scopus2-s2.0-78650731792en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpageM28en_US
dc.identifier.urihttps://doi.org/10.1107/S160053681005004X
dc.identifier.urihttps://hdl.handle.net/20.500.14619/6021
dc.identifier.volume67en_US
dc.identifier.wosWOS:000285628900030en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Crystallographic Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectCrystalen_US
dc.subjectCopperen_US
dc.titleTetrakis[?-4-(diethylamino)benzoato-?2O:O?]bis[(N,N-diethylnicotinamide-?N1)cobalt(II)]en_US
dc.typeArticleen_US

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