ZIF-8 decorated FeMo nanoparticles: H2 Production from the catalytic hydrolysis of ammonia-borane

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dc.authoridYurderi, Mehmet/0000-0002-0233-8940
dc.contributor.authorYilmaz, Can
dc.contributor.authorYildirim, Huseyin Ali
dc.contributor.authorTop, Tuba
dc.contributor.authorYurderi, Mehmet
dc.contributor.authorZahmakiran, Mehmet
dc.date.accessioned2024-09-29T15:50:40Z
dc.date.available2024-09-29T15:50:40Z
dc.date.issued2024
dc.departmentKarabük Üniversitesien_US
dc.description.abstractAmmonia-Borane (AB) is considered a promising solid hydrogen storage material due to its high hydrogen content (19.6 wt%) and its use for safe hydrogen transport. The most effective way to produce H-2 from AB is to perform the hydrolysis reaction in the presence of a suitable catalyst. In this study, Fe0.2Mo0.8/ZIF-8 nanocatalyst was synthesized in two steps: (i) synthesis by following the colloidal synthesis technique by thermal decomposition of Mo(CO)(6) and Fe(acac)(3) in the presence of OM and ODE at high temperatures, and (ii) the resulting colloidal Fe0.2Mo0.8 NPs were decorated into ZIF-8. The as-prepared Fe0.2Mo0.8/ZIF-8 catalyst was identified using advanced characterization techniques such as ICP-OES, P-XRD, SEM, SEM-EDX, TEM, TEM-EDX, XPS, and BET. The catalytic activities of the Fe0.2Mo0.8/ZIF-8 catalyst in the hydrolysis of AB were investigated in different parameters (temperature, catalyst [Fe0.2Mo0.8] and substrate [H3NBH3] concentration, and recyclability). The results show that high crystallinity Fe0.2Mo0.8 NPs with a uniform 1.31 +/- 0.13 nm distribution were formed on the ZIF-8 surface. Fe0.2Mo0.8/ZIF-8 catalyst provides a maximum H-2 generation rate of 184.2 mLH(2) (g catalyst)(-1) (min)(-1) at 343 K. This uniquely cost-effective, active and durable Fe0.2Mo0.8/ZIF-8 catalyst has strong potential for H-2-based fuel cell (PEM: Proton Exchange Membrane) applications where AB is a suitable H-2 carrier.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkiye [1919B012109692]en_US
dc.description.sponsorshipResearch Fund of the Scientific and Technological Research Council of Turkiye,Grant/Award Number: 1919B012109692en_US
dc.identifier.doi10.1002/ep.14439
dc.identifier.issn1944-7442
dc.identifier.issn1944-7450
dc.identifier.scopus2-s2.0-85195565573en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1002/ep.14439
dc.identifier.urihttps://hdl.handle.net/20.500.14619/3677
dc.identifier.wosWOS:001241851000001en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofEnvironmental Progress & Sustainable Energyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectammonia-boraneen_US
dc.subjecthydrogen productionen_US
dc.subjectironen_US
dc.subjectmolybdenumen_US
dc.subjectnanoparticlesen_US
dc.subjectzeolitic imidazolate framework (ZIF-8)en_US
dc.titleZIF-8 decorated FeMo nanoparticles: H2 Production from the catalytic hydrolysis of ammonia-boraneen_US
dc.typeArticleen_US

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