Copper(II) and Zinc(II) coordination polymers based on glutaric acid and 1,2-bis(4-pyridyl)ethylene: Hydrothermal synthesis, characterization and thermal behaviors

Basit Öğe Kaydı
dc.authoridArslan Bicer, Figen/0000-0002-4024-8233
dc.authoridYESILEL, Okan Zafer/0000-0002-2284-1578
dc.contributor.authorBicer, Figen Arslan
dc.contributor.authorCoskum, Ferihan Tatas
dc.contributor.authorSalun, Busra
dc.contributor.authorOzdemir, Ilknur
dc.contributor.authorArici, Mursel
dc.date.accessioned2024-09-29T16:00:26Z
dc.date.available2024-09-29T16:00:26Z
dc.date.issued2023
dc.departmentKarabük Üniversitesien_US
dc.description.abstract1,2-bis(4-pyridyl)ethylene (dpe) and glutaric acid (H2glu) with Cu(II) and Zn(II) afforded two coordination polymers namely, [Cu(mu 3-glu)(mu-dpe)]n (1) and [Zn(mu 3-glu)(mu-dpe)0.5]n (2), and they were characterized by elemental analysis, IR spectroscopies, single crystal X-ray diffraction and powder X-ray diffraction (PXRD) techniques. X-ray diffraction studies have shown that complex 1 crystallizes in the triclinic system, in the P-1 space group, while complex 2 crystallizes in the C2/c space group in the monoclinic system. In complexes 1 and 2, the glu ligand adopts tetradentate coordination mode that one carboxylate group bidentate, other carboxylate group bis(monodentate)-bridging. Complex 1 displayed 2D network with {44.62} point symbol and sql topology which is extended into a 3D supramolecular framework by C- HMIDLINE HORIZONTAL ELLIPSISO hydrogen bonds interactions. Complex 2 featured a 3D network that two identical 3D self-penetrating frameworks interpenetrate each other in a 2-fold (3D+3D -> 3D) mode, with a pcu; 6/4/c1; sqc1 topology with the point symbol of {412.63}. The optical band gap energy values calculated by the Kubelka-Munk function for 1 and 2 observed at 3.20 and 3.24 eV, respectively. Moreover, the thermal properties of the complexes were investigated in the study.en_US
dc.description.sponsorshipTUBITAK 2209 University Students Research Projects Support Programen_US
dc.description.sponsorshipThis work was supported by TUBITAK 2209 University Students Research Projects Support Program.en_US
dc.identifier.doi10.1016/j.molstruc.2023.136561
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85171150793en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2023.136561
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5142
dc.identifier.volume1294en_US
dc.identifier.wosWOS:001076078400001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofJournal of Molecular Structureen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectGlutaric aciden_US
dc.subject2-bis(4-pyridyl)ethyleneen_US
dc.subjectCopper(II) and zinc(II) complexesen_US
dc.subjectMetal-organic frameworksen_US
dc.subjectThermal studyen_US
dc.titleCopper(II) and Zinc(II) coordination polymers based on glutaric acid and 1,2-bis(4-pyridyl)ethylene: Hydrothermal synthesis, characterization and thermal behaviorsen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu