Aquabis(4-formylbenzoato-?2O1,O1?)bis(isonicotinamide-?N1)cadmium(II) monohydrate

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dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.contributor.authorHokelek, Tuncer
dc.contributor.authorYilmaz, Filiz
dc.contributor.authorTercan, Baris
dc.contributor.authorGurgen, Ferdi
dc.contributor.authorNecefoglu, Hacali
dc.date.accessioned2024-09-29T16:03:15Z
dc.date.available2024-09-29T16:03:15Z
dc.date.issued2009
dc.departmentKarabük Üniversitesien_US
dc.description.abstractThe asymmetric unit of the title Cd-II complex, [Cd(C8H5O3)(2)(-)(C6H6N2O)(2)(H2O)]center dot H2O, contains two 4-formylbenzoate (FB), two isonicotinamide (INA) ligands, one coordinated and one uncoordinated water molecule; the FB ions act as bidentate ligands. The coordination number of the Cd(II) atom is seven within a CdO5N2 donor set. Intramolecular O-H center dot center dot center dot O hydrogen bonds link the uncoordinated water molecules to the carboxyl groups. The dihedral angle between the carboxylate groups and the adjacent benzene rings are 17.53 (13) and 16.55 (14)degrees. In the crystal structure, intermolecular O-H center dot center dot center dot O, N-H center dot center dot center dot O, N-H center dot center dot center dot N and C-H center dot center dot center dot O hydrogen bonds link the molecules into a supramolecular structure. The amide group of one of the INA ligands is disordered over two orientations, with an occupancy ratio of 0.759 (3):0.241 (3).en_US
dc.identifier.doi10.1107/S1600536809042640
dc.identifier.endpageU1594en_US
dc.identifier.issn2056-9890
dc.identifier.pmid21578154en_US
dc.identifier.scopus2-s2.0-70449411039en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpageM1416en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536809042640
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5990
dc.identifier.volume65en_US
dc.identifier.wosWOS:000271906600123en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Crystallographic Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleAquabis(4-formylbenzoato-?2O1,O1?)bis(isonicotinamide-?N1)cadmium(II) monohydrateen_US
dc.typeArticleen_US

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