H-bonding behavior of ethylene oxide within the clathrate hydrates revisited: Experiment and theory

Küçük Resim Yok

Tarih

2020

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Elsevier

Erişim Hakkı

info:eu-repo/semantics/openAccess

Özet

FTIR spectroscopy has been used to reexplore the nonclassical behavior of ethylene oxide (EO) within the large cages of clathrate hydrates. In most of the spectroscopic studies of EO within the clathrate hydrate cages, the classical EO bands attributed to the C-O stretch mode of EO were misassigned. Therefore, the all-vapor subsecond approach to clathrate-hydrate formation combined with computational studies was used to reexamine spectroscopic characteristics of EO molecules in which they can be either in classical or nonclassical forms.

Açıklama

Anahtar Kelimeler

Clathrate hydrates, Gas hydrates, Ethylene oxide, FTIR spectroscopy

Kaynak

Chemical Physics Letters

WoS Q Değeri

Q2

Scopus Q Değeri

Q2

Cilt

754

Sayı

Künye