Synthesis and Characterization of Zinc Fluoroborate from Zinc Fluoride and Boron by Mechanochemical Reaction

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dc.contributor.authorAydin, Duygu Y.
dc.contributor.authorGuru, Metin
dc.contributor.authorIpek, Dilek
dc.contributor.authorOzyurek, Dursun
dc.date.accessioned2024-09-29T15:54:44Z
dc.date.available2024-09-29T15:54:44Z
dc.date.issued2017
dc.departmentKarabük Üniversitesien_US
dc.description.abstractThis paper deals with characterization and synthesis of zinc fluoroborate from zinc fluoride and boron by mechanochemical reaction. Zinc fluoroborate is widely used in high technological areas such as textile, chemical reaction, plating solution, and glass. In this study, zinc fluoroborate has been synthesized via high-energy ball milling method. The effect of reactant mol ratio (B/ and ball milling period was investigated on the product yield. After completion of the reaction, the product in the reaction mixture (including excess reactant and side products) was purified by the extraction with water. The samples were characterized by FT-IR and ion-selective electrode. SEM and EDX analyses were took place. Decomposition of sample was characterized by TG-DTA. The sample was sintered at 300- to compare the data with TG-DTA. The results showed that decomposition of B-F bond started at . As a result of these experiments, maximum yield was obtained at 0.8 molar ratio and 3000 min. of mechanochemical reaction duration with the use of ball milling. Eighty-three percentage pure zinc fluoroborate was produced by adding the purification step.en_US
dc.description.sponsorshipEti Mine Works General Managements [2014.C.11.0010.15]; Eti Mine Works of Turkeyen_US
dc.description.sponsorshipThis work was supported by Eti Mine Works General Managements under Project Number 2014.C.11.0010.15. The authors are grateful to Eti Mine Works of Turkey for financial support and Gazi University for laboratory facilities usage.en_US
dc.identifier.doi10.1007/s13369-017-2559-2
dc.identifier.endpage4416en_US
dc.identifier.issn2193-567X
dc.identifier.issn2191-4281
dc.identifier.issue10en_US
dc.identifier.scopus2-s2.0-85028376406en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage4409en_US
dc.identifier.urihttps://doi.org/10.1007/s13369-017-2559-2
dc.identifier.urihttps://hdl.handle.net/20.500.14619/4239
dc.identifier.volume42en_US
dc.identifier.wosWOS:000408695500019en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringer Heidelbergen_US
dc.relation.ispartofArabian Journal For Science and Engineeringen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectZinc fluoroborateen_US
dc.subjectMechanochemical reactionen_US
dc.subjectBall millingen_US
dc.subjectZnF2en_US
dc.subjectBoronen_US
dc.titleSynthesis and Characterization of Zinc Fluoroborate from Zinc Fluoride and Boron by Mechanochemical Reactionen_US
dc.typeArticleen_US

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