Poly[[diaquamanganese(II)]-bis(?-4-fluorobenzoato-?2O:O?)]

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dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.authoridOzturkkan, Fureya Elif/0000-0001-6376-4161
dc.contributor.authorNecefoglu, Hacali
dc.contributor.authorOzbek, Fureya Elif
dc.contributor.authorOzturk, Vijdan
dc.contributor.authorTercan, Baris
dc.contributor.authorHokelek, Tuncer
dc.date.accessioned2024-09-29T16:03:22Z
dc.date.available2024-09-29T16:03:22Z
dc.date.issued2011
dc.departmentKarabük Üniversitesien_US
dc.description.abstractIn the crystal structure of the title complex, [Mn(C7H4FO2)(2)-(H2O)(2)](n), the Mn-II atom is located on an inversion centre. It is coordinated by two water molecules in the apical directions and four 4-fluorobenzoate (PFB) anions, bridging the symmetry related Mn atoms in the basal plane to form an infinite two-dimensional polymeric structure parallel to (100). The four O atoms of the PFB anions around the Mn-II atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two O atoms of the water molecules. The dihedral angle between the carboxylate group and the adjacent benzene ring is 27.29 (16)degrees. The O-H center dot center dot center dot O hydrogen bonds further connect the manganese-carboxylate units. pi-pi contacts between the benzene rings [centroid-centroid distance = 3.6894 (15) angstrom] further stabilize the crystal structure.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey [108 T657]en_US
dc.description.sponsorshipThe authors are indebted to Anadolu University and the Medicinal Plants and Medicine Research Centre of Anadolu University, Eskisehir, Turkey, for the use of the X-ray diffractometer. This work was supported financially by the Scientific and Technological Research Council of Turkey (grant No. 108 T657).en_US
dc.identifier.doi10.1107/S1600536811021921
dc.identifier.endpageU1690en_US
dc.identifier.issn2056-9890
dc.identifier.pmid21836830en_US
dc.identifier.scopus2-s2.0-79960064838en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpageM1003en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536811021921
dc.identifier.urihttps://hdl.handle.net/20.500.14619/6035
dc.identifier.volume67en_US
dc.identifier.wosWOS:000294663000141en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Crystallographic Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titlePoly[[diaquamanganese(II)]-bis(?-4-fluorobenzoato-?2O:O?)]en_US
dc.typeArticleen_US

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