Synthesis of catena-Poly[[di-aqua(2,2?-bipyridine)copper (II)]-?2-sulfato-?2O:O'] 1D coordination polymer and [di-chloro (2,2?-bipyridine)copper(II)] complex, redetermination of their crystal structures

Basit Öğe Kaydı
dc.authoridYILMAZ, ISMAIL/0000-0002-0139-0122
dc.contributor.authorYilmaz, Ismail
dc.date.accessioned2024-09-29T16:00:33Z
dc.date.available2024-09-29T16:00:33Z
dc.date.issued2024
dc.departmentKarabük Üniversitesien_US
dc.description.abstractThe title compounds [Cu(bpy)(H2O)(2)(SO4)](n )(1) and [Cu(bpy)Cl2] (2) were successfully synthesized, and their crystal structures were redetermined as some corrections were needed. The Cu(II) centers in 1 are coordinated in elongated octahedral geometry by the two nitrogen atoms of a bpy ligand and four oxygen atoms belonging to aqua molecules and sulfato ligands, forming a polymeric chain by bridging the sulfato ligands. The Cu(II) center in 2 is coordinated by the two chloride ions and the two nitrogen atoms of the bipyridine ligand, forming a distorted square planar geometry. The [Cu(bpy)(H2O)(2)(SO4)](n )complex crystallizes in the monoclinic crystal system with space group C2/c. The unit cell parameters were determined to be a =15.154(3) angstrom, b =12.477(3) angstrom, c = 7.0158(14) angstrom, alpha = 90 degrees, beta = 105.873(12)degrees, gamma = 90 degrees, V = 1276.0(5) angstrom(3), Z = 4. The Cu-N, Cu-O(aqua) and Cu-O (sulfate) bond lengths are 2.000(3) angstrom, 1.978(2) angstrom and 2.464(2) angstrom, respectively. The [Cu(bpy)Cl-2] complex crystallizes in the monoclinic crystal system with space group I2/a. The unit cell parameters were determined to be a = 7.306(2) angstrom, b = 9.016(2) angstrom, c = 15.879(6) angstrom, alpha = 90, fi = 92.141(15), gamma = 90 degrees, V =1045.2(5) angstrom(3), Z = 4. The Cu-N and Cu-Cl bond lengths are 2.031(5) angstrom and 2.2662(17) angstrom, respectively.en_US
dc.description.sponsorshipKarabuk University [KBU-BAP-13/2-DS-051]en_US
dc.description.sponsorshipThe author is grateful to Karabuk University for grant KBU-BAP-13/2-DS-051. The author also acknowledges the Scientific and Technological Research Application and Research Center, Sinop University, Turkey, using the Bruker D8 QUEST diffractometer.en_US
dc.identifier.doi10.1016/j.poly.2023.116816
dc.identifier.issn0277-5387
dc.identifier.issn1873-3719
dc.identifier.scopus2-s2.0-85183349307en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1016/j.poly.2023.116816
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5221
dc.identifier.volume250en_US
dc.identifier.wosWOS:001154794400001en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofPolyhedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCopper(II) complexen_US
dc.subjectBipyridineen_US
dc.subjectCoordination polymeren_US
dc.subjectCrystal structureen_US
dc.subjectRedeterminationen_US
dc.titleSynthesis of catena-Poly[[di-aqua(2,2?-bipyridine)copper (II)]-?2-sulfato-?2O:O'] 1D coordination polymer and [di-chloro (2,2?-bipyridine)copper(II)] complex, redetermination of their crystal structuresen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu