4-[2-(2,2-Dimethyl-4,6-dioxo-1,3-dioxan-5-ylidene)hydrazin-1-yl]benzonitrile

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dc.authoridERMIS, EMEL/0000-0003-3052-4123
dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.contributor.authorColak, Naki
dc.contributor.authorYildirir, Yilmaz
dc.contributor.authorTercan, Baris
dc.contributor.authorErmis, Emel
dc.contributor.authorHokelek, Tuncer
dc.date.accessioned2024-09-29T16:03:18Z
dc.date.available2024-09-29T16:03:18Z
dc.date.issued2010
dc.departmentKarabük Üniversitesien_US
dc.description.abstractIn the title compound, C13H11N3O4, the dioxane ring adopts an envelope conformation with the C atom bonded to the dimethyl group in the flap position [deviation = 0.613 (1) angstrom]. The nitrile group and the attached benzene ring are roughly coplanar [maximum deviation = 0.087 (1) angstrom]. An intramolecular N-H center dot center dot center dot O hydrogen bond involving the hydrazinyl group generates an S(6) ring. The N-N and C-N bond lengths indicate that the compound may be a mixture of the azo and hydrazone tautomeric forms but the presence of the N-bound H atom supports the hydrazone form. The crystal structure is stabilized by weak intermolecular C-H center dot center dot center dot O, C-H center dot center dot center dot N and C-H center dot center dot center dot pi interactions.en_US
dc.identifier.doi10.1107/S1600536810024025
dc.identifier.endpageU418en_US
dc.identifier.issn2056-9890
dc.identifier.pmid21587996en_US
dc.identifier.scopus2-s2.0-77954388328en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpageO1784en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536810024025
dc.identifier.urihttps://hdl.handle.net/20.500.14619/6011
dc.identifier.volume66en_US
dc.identifier.wosWOS:000279389400030en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Crystallographic Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectGratingsen_US
dc.title4-[2-(2,2-Dimethyl-4,6-dioxo-1,3-dioxan-5-ylidene)hydrazin-1-yl]benzonitrileen_US
dc.typeArticleen_US

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