The microwave-assisted synthesis and structural characterization of novel, dithia-bridged polymeric phthalocyanines containing a substituted thiophenylamine Schiff base

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dc.authoridDegirmencioglu, Ismail/0000-0002-7964-0427
dc.authoridBayrak, Riza/0000-0002-0398-7694
dc.contributor.authorDegirmencioglu, Ismail
dc.contributor.authorBayrak, Riza
dc.contributor.authorEr, Mustafa
dc.contributor.authorSerbest, Kerim
dc.date.accessioned2024-09-29T15:55:16Z
dc.date.available2024-09-29T15:55:16Z
dc.date.issued2009
dc.departmentKarabük Üniversitesien_US
dc.description.abstractNovel polymeric metal-free and metallo(Cu(II), Co(II), Ni(II), Zn(II) and Pb(II))-phthalocyanine complexes were synthesized using microwave irradiation and the products were purified by several (crystallization and preparative thin layer) techniques. The newly prepared compounds were characterized by a combination of elemental analyses, IR, H-1/C-13 NMR,H-1-H-1 COSY, MS and UV-Vis spectroscopy. In order to better understand the spectroscopy data (especially for H-1/C-13 NMR and H-1-H-1 COSY techniques), computational calculations were used for characterization at DFT/6-31G(d) level. The electronic spectra exhibited an intense pi -> pi* transition with characteristic Q and B bands of the phthalocyanine core. (C) 2009 Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipResearch Fund of Karadeniz Technical University, (Trabzon/Turkey) [2006.111.002.4]en_US
dc.description.sponsorshipThis work was supported by the Research Fund of Karadeniz Technical University, Project No. 2006.111.002.4 (Trabzon/Turkey).en_US
dc.identifier.doi10.1016/j.dyepig.2009.03.011
dc.identifier.endpage58en_US
dc.identifier.issn0143-7208
dc.identifier.issn1873-3743
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-67349262374en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage51en_US
dc.identifier.urihttps://doi.org/10.1016/j.dyepig.2009.03.011
dc.identifier.urihttps://hdl.handle.net/20.500.14619/4561
dc.identifier.volume83en_US
dc.identifier.wosWOS:000267414100006en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Sci Ltden_US
dc.relation.ispartofDyes and Pigmentsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPolymeric phthalocyaninesen_US
dc.subjectMicrowave-assisteden_US
dc.subjectSubstituted Schiff baseen_US
dc.subjectSynthesisen_US
dc.subjectPhthalodinitrileen_US
dc.subjectSpectroscopic identificationen_US
dc.titleThe microwave-assisted synthesis and structural characterization of novel, dithia-bridged polymeric phthalocyanines containing a substituted thiophenylamine Schiff baseen_US
dc.typeArticleen_US

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