Bis(4-fluorobenzoato)-?2O,O?;?O-(4-fluorobenzoic acid-?O)bis(nicotinamide-?N1)copper(II)

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dc.authoridOzturkkan, Fureya Elif/0000-0001-6376-4161
dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.contributor.authorNecefoglu, Hacali
dc.contributor.authorOzbek, Fureya Elif
dc.contributor.authorOzturk, Vijdan
dc.contributor.authorTercan, Baris
dc.contributor.authorHokelek, Tuncer
dc.date.accessioned2024-09-29T16:03:22Z
dc.date.available2024-09-29T16:03:22Z
dc.date.issued2011
dc.departmentKarabük Üniversitesien_US
dc.description.abstractIn the title Cu-II complex, [Cu(C7H4FO2)(2)(C7H5FO2)(C6H6N2O)(2)], the Cu-II cation is coordinated by two N atoms of two nicotinamide (NA) ligands, and by four O atoms from two 4-fluorobenzoate (PFB) anions and one 4-fluorobenzoic acid (PFBA) molecule, in a distorted octahedral geometry. In the molecule, two Cu-O bond lengths are significantly longer than the other two. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 11.08 (14), 7.62 (13) and 5.73 (11)degrees, while the benzene rings are oriented at dihedral angles of 15.62 (6), 33.71 (8) and 26.60 (8)degrees. In the crystal structure, extensive N-H center dot center dot center dot O, C-H center dot center dot center dot F and C-H center dot center dot center dot O hydrogen bonds link the molecules into a three-dimensional network. pi-pi contacts between the benzene rings [centroid-to-centroid distances = 3.5517 (15), 3.8456 (14) and 3.9265 (13) angstrom] further stabilize the crystal structure.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey [108T657]en_US
dc.description.sponsorshipThe authors are indebted to Anadolu University and the Medicinal Plants and Medicine Research Centre of Anadolu University, Eskisehir, Turkey, for the use of the X-ray diffractometer. This work was financially supported by the Scientific and Technological Research Council of Turkey (grant No. 108T657).en_US
dc.identifier.doi10.1107/S1600536811020897
dc.identifier.issn2056-9890
dc.identifier.pmid21836879en_US
dc.identifier.scopus2-s2.0-79960045466en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536811020897
dc.identifier.urihttps://hdl.handle.net/20.500.14619/6033
dc.identifier.volume67en_US
dc.identifier.wosWOS:000294663000048en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Crystallographic Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectCrystalen_US
dc.titleBis(4-fluorobenzoato)-?2O,O?;?O-(4-fluorobenzoic acid-?O)bis(nicotinamide-?N1)copper(II)en_US
dc.typeArticleen_US

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