Diaquabis(2-bromobenzoato-?O)bis(N,N-diethylnicotinamide-?N1)nickel(II)

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dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.authoridOzturkkan, Fureya Elif/0000-0001-6376-4161
dc.contributor.authorHokelek, Tuncer
dc.contributor.authorYilmaz, Filiz
dc.contributor.authorTercan, Baris
dc.contributor.authorOzbek, F. Elif
dc.contributor.authorNecefoglu, Hacali
dc.date.accessioned2024-09-29T16:03:14Z
dc.date.available2024-09-29T16:03:14Z
dc.date.issued2009
dc.departmentKarabük Üniversitesien_US
dc.description.abstractIn the monomeric centrosymmetric title Ni-II complex, [Ni(C7H4BrO2)(2)(C10H14N2O)(2)(H2O)(2)], the Ni-II ion is located on an inversion center. The asymmetric unit contains one 2-bromobenzoate ligand, one diethylnicotinamide (DENA) ligand and one coordinated water molecule. The four O atoms in the equatorial plane around the Ni-II ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by two N atoms of two DENA ligands in the axial positions. The dihedral angle between the benzene ring and the attached carboxylate group is 87.73 (15)degrees, while the pyridine and benzene rings are oriented at a dihedral angle of 42.48 (7)degrees. In the crystal structure, O-H center dot center dot center dot O hydrogen bonds link the molecules into a two-dimensional network parallel to (10 (1) over bar). In addition, C-H center dot center dot center dot O hydrogen bonds are observed.en_US
dc.identifier.doi10.1107/S1600536809021795
dc.identifier.endpageU739en_US
dc.identifier.issn2056-9890
dc.identifier.pmid21582698en_US
dc.identifier.scopus2-s2.0-67650854423en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpageM766en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536809021795
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5978
dc.identifier.volume65en_US
dc.identifier.wosWOS:000267385300056en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Crystallographic Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectMolecular-Structureen_US
dc.subjectCrystalen_US
dc.titleDiaquabis(2-bromobenzoato-?O)bis(N,N-diethylnicotinamide-?N1)nickel(II)en_US
dc.typeArticleen_US

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