Synthesis, structural characterization, and thermal properties of octahedral diperchlorato complexes of copper(II) with the chelating 2-aminomethylpiperidine and 2-aminomethylpyridine ligands

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dc.authoridYILMAZ, ISMAIL/0000-0002-0139-0122
dc.contributor.authorYilmaz, Ismail
dc.date.accessioned2024-09-29T16:03:02Z
dc.date.available2024-09-29T16:03:02Z
dc.date.issued2023
dc.departmentKarabük Üniversitesien_US
dc.description.abstractTwo distorted octahedral copper(II) coordination compounds; [Cu(AMPp)(2)(OClO3)(2)] (1) and [Cu(AMP)(2)(OClO3)(2)] (2) (2-aminomethylpiperidine and 2-aminomethylpyridine) have been synthesized on a SP Sephadex C-25 cation exchanger resin for high purity. Their structures have been determined by single-crystal X-ray diffraction, fourier transform infrared spectroscopy, and also thermal analysis. In both structures, the metal center adopts an elongated octahedral geometry in which two chelating amine ligands occupy the square plane in a trans-position, and two perchlorate ligands occupy the axial sites. The thermal stability of both complexes is relatively high. However, the thermal stability of 2 with the aromatic ring was 12 degrees C higher, due to intermolecular hydrogen bonds, pi MIDLINE HORIZONTAL ELLIPSIS pi, and pi MIDLINE HORIZONTAL ELLIPSISO interactions.en_US
dc.description.sponsorshipKarabuk University [KBU-BAP-13/2DS-051]en_US
dc.description.sponsorshipThe author is grateful to Karabuk University for grant KBU-BAP-13/2DS-051. The author also acknowledges the Scientific and Technological Research Application and Research Center, Sinop University, Turkey, using the Bruker D8 QUEST diffractometer. The author thanks Prof. Dr. Abdurrahman SENGUL (Department of Chemistry, Faculty of Arts and Sciences, Zonguldak Bulent Ecevit University) for helpful discussion and proofreading.en_US
dc.identifier.doi10.1080/24701556.2022.2068589
dc.identifier.endpage339en_US
dc.identifier.issn2470-1556
dc.identifier.issn2470-1564
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-85132670786en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage333en_US
dc.identifier.urihttps://doi.org/10.1080/24701556.2022.2068589
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5847
dc.identifier.volume53en_US
dc.identifier.wosWOS:000788970400001en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherTaylor & Francis Incen_US
dc.relation.ispartofInorganic and Nano-Metal Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCopper(II) complexen_US
dc.subjectaminomethylpiperidineen_US
dc.subjectaminomethylpyridineen_US
dc.subjectperchloratoen_US
dc.subjectthermal stabilityen_US
dc.titleSynthesis, structural characterization, and thermal properties of octahedral diperchlorato complexes of copper(II) with the chelating 2-aminomethylpiperidine and 2-aminomethylpyridine ligandsen_US
dc.typeArticleen_US

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