The synthesis and characterization of [M(salen/salophen/saldeta)] [M=Cr(III), Mn(III) or Fe(III)] capped s-triazine cored tripodal trinuclear Schiff bases complexes

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dc.authoridISCI, Berkman/0000-0002-8825-072X
dc.authoridUYSAL, Saban/0000-0003-1061-6143
dc.contributor.authorIsci, Berkman
dc.contributor.authorUysal, Saban
dc.date.accessioned2024-09-29T15:51:15Z
dc.date.available2024-09-29T15:51:15Z
dc.date.issued2018
dc.departmentKarabük Üniversitesien_US
dc.description.abstractLigand complexes ([M(salen/salophen)](2)O, [M(saldeta)]Cl shortened as LC, M=Cr(III), Mn(III) or Fe(III)), have been synthesized. 2,4,6-tris(4-formylphenoxy)-1,3,5-triazine (3) was synthesized with the reaction of p-hydroxybenzaldehyde (2) and cyanuric chloride (1). 2,4,6-tris(4-(4-carboxyphenylimino)phenoxy)-1,3,5-triazine (5) was synthesized with the reaction of 2,4,6-tris(4-formylphenoxy)-1,3,5-triazine (3) and 4-aminobenzoic acid (4). 2,4,6-tris(4-(4-carboxyphenylimino)phenoxy)-1,3,5-triazine was treated with SOCl2 in CH3CN, and 2,4,6-tris(4-(4-chloroformylphenylimino)phenoxy)-1,3,5-triazine (6) was obtained. 2,4,6-tris(4-(4-chloroformylphenylimino)phenoxy)-1,3,5-triazine was reacted with 4-aminobenzoic acid or 4-hydroxbenzoic acid in CH3CN, and 2,4,6-tris(4-(4-(4-carboxyphenylamido)phenylimino)phenoxy)-1,3,5-triazine (8) and 2,4,6-tris(4-(4-(4-carboxyphenylformato)phenylimino)phenoxy)-1,3,5-triazine (9) were obtained. s-Triazine cored tripodal trinuclear Schiff bases complexes were synthesized with the reaction of 8 and/or 9 and ligand complexes. The complexes have been characterized as low-spin (S=1/2) distorted octahedral Fe(III)Salen/Salophen, low-spin (S=1) distorted octahedral Mn(III)Salen/Salophen, high-spin (S=5/2) distorted octahedral Fe(III)Saldeta, high-spin (S=2) distorted octahedral Mn(III)Saldeta and (S=3/2) distorted octahedral Cr(III)Salen/Salophen/Saldeta bridged by COO- groups. The structure of all ligand and complexes were identified by using elemental analysis, thermal analyses (TGA-DTG), magnetic susceptibility, ESI-MS, ICP-AES, UV-Vis, H-1-NMR, C-13-NMR and FT-IR spectral data. [GRAPHICS] .en_US
dc.description.sponsorshipKarabuk University Coordinator of Scientific Research Projects [KBUBAP-17-YL-035]en_US
dc.description.sponsorshipThis study was produced from Berkman Isci's M. Sc. Thesis. The authors are grateful to Karabuk University Coordinator of Scientific Research Projects (Project No: KBUBAP-17-YL-035) for financial support in order to carry on this research work.en_US
dc.identifier.doi10.1007/s10847-018-0844-7
dc.identifier.endpage299en_US
dc.identifier.issn1388-3127
dc.identifier.issn1573-1111
dc.identifier.issue3-4en_US
dc.identifier.scopus2-s2.0-85057059390en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage281en_US
dc.identifier.urihttps://doi.org/10.1007/s10847-018-0844-7
dc.identifier.urihttps://hdl.handle.net/20.500.14619/3967
dc.identifier.volume92en_US
dc.identifier.wosWOS:000451049300005en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of Inclusion Phenomena and Macrocyclic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCyanuric chlorideen_US
dc.subjectSalenen_US
dc.subjectSalophenen_US
dc.subjectSaldetaen_US
dc.subjectTripodal trinuclear complexesen_US
dc.titleThe synthesis and characterization of [M(salen/salophen/saldeta)] [M=Cr(III), Mn(III) or Fe(III)] capped s-triazine cored tripodal trinuclear Schiff bases complexesen_US
dc.typeArticleen_US

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