Diaquabis(4-methylbenzoato-?O)bis(nicotinamide-?N1)manganese(II)

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dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.contributor.authorNecefoglu, Hacali
dc.contributor.authorCimen, Efdal
dc.contributor.authorTercan, Baris
dc.contributor.authorDal, Hakan
dc.contributor.authorHokelek, Tuncer
dc.date.accessioned2024-09-29T16:03:16Z
dc.date.available2024-09-29T16:03:16Z
dc.date.issued2010
dc.departmentKarabük Üniversitesien_US
dc.description.abstractIn the mononuclear title complex, [Mn(C8H7O2)(2)(C6H6N2O)(2)-(H2O)(2)], the Mn-II ion is located on a crystallographic inversion center. The asymmetric unit contains one 4-methylbenzoate anion, one nicotinamide (NA) ligand and one coordinated water molecule. The four O atoms in the equatorial plane around the Mn-II ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the attached benzene ring is 9.01 (7)degrees, while the pyridine and benzene rings are oriented at a dihedral angle of 42.44 (5)degrees. In the crystal structure, intermolecular O-H center dot center dot center dot O, N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds, and O-H center dot center dot center dot pi and C-H center dot center dot center dot pi interactions link the molecules into a two-dimensional network parallel to (001).en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey [108 T657]en_US
dc.description.sponsorshipThe authors are indebted to Anadolu University and the Medicinal Plants and Medicine Research Centre of Anadolu University, Eskisehir, Turkey, for the use of X-ray diffractometer. This work was supported financially by the Scientific and Technological Research Council of Turkey (grant No. 108 T657).en_US
dc.identifier.doi10.1107/S1600536810011815
dc.identifier.endpageU245en_US
dc.identifier.issn2056-9890
dc.identifier.pmid21578994en_US
dc.identifier.scopus2-s2.0-77952064346en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpageM490en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536810011815
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5999
dc.identifier.volume66en_US
dc.identifier.wosWOS:000277240600013en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Crystallographic Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleDiaquabis(4-methylbenzoato-?O)bis(nicotinamide-?N1)manganese(II)en_US
dc.typeArticleen_US

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