The synthesis and characterization of (MSalen/salophen/saldeta/salpy) [M=Fe(III) or Cr(III)] capped heteromultinuclear schiff bases-dioxime Ni(II) complexes: Their thermal and magnetic behaviours

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dc.authoridUYSAL, Saban/0000-0003-1061-6143
dc.authoridKOC, ZIYA ERDEM/0000-0002-5875-9779
dc.contributor.authorUysal, Saban
dc.contributor.authorKoc, Ziya Erdem
dc.date.accessioned2024-09-29T16:00:26Z
dc.date.available2024-09-29T16:00:26Z
dc.date.issued2018
dc.departmentKarabük Üniversitesien_US
dc.description.abstractChlorophenylglyoxime and Ligand Complexes ([M(Salen/Salophen)](2)O, [M(Saldeta/Salpy)Cl] shortened as LC, M = Fe(III) or Cr(III)) have been synthesized. 3,5-dicarboxyanilinophenylglyoxime (5) and 4-carboxyphenylhydrazinophenylglyoxime (6) have been synthesized with the reaction of chlorophenylglyoxime and 5-aminoisophtalalic acid or 4-hydrazinobenzoic acid. [M(Salen/Salophen/Saldeta/ Salpy)-3,5-dicarboxyanilinophenyl-glyoxime)] (7-14) or [M(Salen/Salophen)-4-carboxyphenylhydrazinophenylglyoxime)] (15-22) have been synthesized from (5) or (6) and LCs. The new heterotrinuclear and pentanuclear complexes (23-38) have been obtained from (7-22) and Ni(II) salt. Then, heteronuclear and BF2+ capped vic-dioxime complexes (39-54) have been synthesized. The complexes have been characterized as low-spin (S=1/2) distorted octahedral [Fe-III(Salen/Salophen)], high-spin (S = 5/2) distorted octahedral [Fe-III(Saldeta/Salpy)] and (S = 3/2) distorted octahedral [Cr-III(Salen/Salophen/Saldeta/Salpy)] bridged by COO- groups. The structure of all ligand and complexes were identified by using elemental analysis, thermal analyses, magnetic susceptibility, LC-MS, ICP-AES, H-1-NMR and FT-IR spectral data. (C) 2018 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.molstruc.2018.03.101
dc.identifier.endpage22en_US
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85046017788en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage14en_US
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2018.03.101
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5128
dc.identifier.volume1165en_US
dc.identifier.wosWOS:000432502800003en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Bven_US
dc.relation.ispartofJournal of Molecular Structureen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectvic-dioximeen_US
dc.subjectSalenen_US
dc.subjectSalophenen_US
dc.subjectSaldetaen_US
dc.subjectSalpyen_US
dc.subjectHeteromultinuclear complexesen_US
dc.titleThe synthesis and characterization of (MSalen/salophen/saldeta/salpy) [M=Fe(III) or Cr(III)] capped heteromultinuclear schiff bases-dioxime Ni(II) complexes: Their thermal and magnetic behavioursen_US
dc.typeArticleen_US

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