Synthesis and Characterizations of s-Triazine Polymeric Complexes Including Epoxy Groups: Investigation of Their Magnetic and Thermal Properties

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dc.authoridtekin, oguzhan/0000-0001-9053-3414
dc.authoridUYSAL, Saban/0000-0003-1061-6143
dc.contributor.authorTekin, Oguzhan
dc.contributor.authorUysal, Saban
dc.date.accessioned2024-09-29T15:51:18Z
dc.date.available2024-09-29T15:51:18Z
dc.date.issued2019
dc.departmentKarabük Üniversitesien_US
dc.description.abstractWe aimed to synthesize and characterize novel salen/salophen capped polymeric complexes including oxirane groups. For this purpose, we used 2,4,6-trichloro-1,3,5-triazine (I) as starting material. 2,4-dichloro,6-(3,4-dihydroxyphenylethylamino)-1,3,5-triazine (II) was synthesized by the reaction of an equivalent (I) and an equivalent dopamine. 2-(3,4-bis(oxiran-2-ylmethoxy)phenethyl)amine,4,6-dichloro-1,3,5-triazin (III) was synthesized by the reaction of two equivalents of epichlorohydrin and an equivalent of (II). [(Salen/Salophen) (Cr(III)/Fe(III))] capped complexes of (III) were synthesized by reaction of the reactants, codded as IV, V, VI and VII. Then, these monomeric complexes were polymerized by using ethylenediamine and o-phenylenediamine in 1,4-dioxane media, codded as VIII, IX, X, XI, XII, XIII, XIV and XV. II and III, monomeric and polymeric complexes were characterized by means of elemental analyses, H-1-NMR (spectrometry) and C-13-NMR (spectrometry), FT-IR spectrometry, ESI-MS and thermal analyses. Metal content in the prepared polymeric complexes was determined by inductively coupled plasma atomic emission spectrophotometer (ICPAES). We also synthesized novel polymeric complexes and investigated their effects on magnetic behaviors of [Cr(III)/Fe(III)(salen/salophen)] capped complexes. The complexes were determined to be low-spin distorted octahedral Fe(III) and distorted octahedral Cr(III).en_US
dc.description.sponsorshipKarabuk University [KBUBAP-17-YL-175]en_US
dc.description.sponsorshipThis study was produced from Oguzhan Tekin's M.Sc. Thesis. The authors are grateful to Karabuk University Coordinator of Scientific Research Projects (Project No: KBUBAP-17-YL-175) for financial support in order to carry out this research work.en_US
dc.identifier.doi10.1007/s10904-019-01132-0
dc.identifier.endpage1715en_US
dc.identifier.issn1574-1443
dc.identifier.issn1574-1451
dc.identifier.issue5en_US
dc.identifier.scopus2-s2.0-85063010785en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage1701en_US
dc.identifier.urihttps://doi.org/10.1007/s10904-019-01132-0
dc.identifier.urihttps://hdl.handle.net/20.500.14619/4001
dc.identifier.volume29en_US
dc.identifier.wosWOS:000481879000027en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of Inorganic and Organometallic Polymers and Materialsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjects-Triazineen_US
dc.subjectSalenen_US
dc.subjectSalophenen_US
dc.subjectEpichlorohydrinen_US
dc.subjectOxiraneen_US
dc.subjectEpoxyen_US
dc.titleSynthesis and Characterizations of s-Triazine Polymeric Complexes Including Epoxy Groups: Investigation of Their Magnetic and Thermal Propertiesen_US
dc.typeArticleen_US

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