IMPROVEMENT OF SELECTIVE COPPER EXTRACTION FROM A HEAT-TREATED CHALCOPYRITE CONCENTRATE WITH ATMOSPHERIC SULPHURIC-ACID LEACHING
dc.contributor.author | Uzun, Elif | |
dc.contributor.author | Zengin, Mustafa | |
dc.contributor.author | Atilgan, Ismail | |
dc.date.accessioned | 2024-09-29T16:06:28Z | |
dc.date.available | 2024-09-29T16:06:28Z | |
dc.date.issued | 2016 | |
dc.department | Karabük Üniversitesi | en_US |
dc.description.abstract | The present work focuses on the extraction of Cu, suitable for production, directly from a leach solution of a chalcopyrite concentrate as an alternative to the conventional smelting and refining method. Firstly, the main aspects of the kinetics of chalcopyrite leaching in a sulphuric-acid solution and transformation reactions of chalcopyrite at high temperatures were briefly reviewed. Secondly, atmospheric-acid leaching experiments were performed as a function of the acid content and temperature under agitation. Direct leaching experiments resulted in very low and scattered Cu recoveries, hence revealing a sulphide passivation layer on the chalcopyrite. In order to get rid of this layer, the sulphides in the chalcopyrite were transformed into sulphates with heat treatment at 500 degrees C prior to the leaching process, in which a high dissolution of species was obtained. Finally, the leaching of the pre-heated concentrate resulted in a 99.82 % Cu extraction. Consequently, optimized process parameters were proposed by comparing the Cu extraction and the increased purity of the pregnant solution without Fe impurities. | en_US |
dc.description.sponsorship | Karabuk University BAP Project; ASYA MADEN Co | en_US |
dc.description.sponsorship | Authors wish to thank ARGETEST Co. for experimental facilities. This work was supported by a grant from the Karabuk University BAP Project and, in part, by ASYA MADEN Co. | en_US |
dc.identifier.doi | 10.17222/mit.2015.091 | |
dc.identifier.endpage | 401 | en_US |
dc.identifier.issn | 1580-2949 | |
dc.identifier.issn | 1580-3414 | |
dc.identifier.issue | 3 | en_US |
dc.identifier.scopus | 2-s2.0-84975092100 | en_US |
dc.identifier.scopusquality | Q3 | en_US |
dc.identifier.startpage | 395 | en_US |
dc.identifier.uri | https://doi.org/10.17222/mit.2015.091 | |
dc.identifier.uri | https://hdl.handle.net/20.500.14619/6846 | |
dc.identifier.volume | 50 | en_US |
dc.identifier.wos | WOS:000385008500017 | en_US |
dc.identifier.wosquality | Q4 | en_US |
dc.indekslendigikaynak | Web of Science | en_US |
dc.indekslendigikaynak | Scopus | en_US |
dc.language.iso | en | en_US |
dc.publisher | Inst Za Kovinske Materiale I In Tehnologie | en_US |
dc.relation.ispartof | Materiali in Tehnologije | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.subject | chalcopyrite concentrate | en_US |
dc.subject | leaching heat treatment | en_US |
dc.subject | passivation layer | en_US |
dc.subject | copper extraction | en_US |
dc.subject | selectivity | en_US |
dc.title | IMPROVEMENT OF SELECTIVE COPPER EXTRACTION FROM A HEAT-TREATED CHALCOPYRITE CONCENTRATE WITH ATMOSPHERIC SULPHURIC-ACID LEACHING | en_US |
dc.type | Article | en_US |