The synthesis and characterization of s-Triazine polymer complexes containing epoxy groups

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dc.authoridORHAN KARAKAYA, NESLIHAN/0000-0002-0425-1275
dc.authoridUYSAL, Saban/0000-0003-1061-6143
dc.contributor.authorKarakaya, Neslihan Orhan
dc.contributor.authorUysal, Saban
dc.date.accessioned2024-09-29T16:00:26Z
dc.date.available2024-09-29T16:00:26Z
dc.date.issued2020
dc.departmentKarabük Üniversitesien_US
dc.description.abstractIt has been synthesized in this study that s-triazine based monomeric complexes including epoxy groups and their polymeric structures. For this reason, cyanuric chloride (I) has been used as starting material. 5-(4,6-dicholoro-2-1,3,5-triazine-2-ylamino)isophtalic acid coded as III has been obtained from the reaction of 5-aminoisophtalic acid II and I at -5 degrees C with sodium bicarbonate in aqua/acetone media. Bis(oxiran-2-ylmethyl)-5-(4,6-dichloro-1,3,5-triazine-2-ylamino)izophtalate coded as V was synthesized from the reaction of epichlorohydrin (IV) and III in aqua/acetone media with KOH at 2 degrees C. In aqua/ ethanol media at 60 degrees C, monomeric metal complexes (VI, VII and VIII) were obtained from the reaction of V and/or Mn+2, Co+2 and Ni+2. s-Triazine based polymeric metal complexes (IX-XIV) were obtained from the reaction of the monomeric metal complexes and 3,4-dihydroxybenzaldehyde/o-phenylenediamine in 1,4-diaxane media with DIPEA at 60 degrees C. The structure of ligands, monomers and polymers were characterized using H-1 NMR and C-13 NMR, FTIR, ESI-MS, UV-vis spectrophotometers, TGA and elemental analyses. Metal contents in the prepared monomeric and polymeric complexes were determined by inductively coupled plasma atomic emission spectrophotometer (ICP-AES). Magnetic behaviors of the synthesized novel monomeric and polymeric complexes were also investigated. And, these compounds were determined to be high-spin distorted octahedral Mn(II), distorted octahedral Co(II) and distorted octahedral Ni(II). (C) 2019 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipKarabuk University Scientific Research Projects Coordinatorship [KBUBAP-17-YL-176]en_US
dc.description.sponsorshipThis study was produced from Neslihan Orhan's M.Sc. Thesis. We acknowledge that this work was financially supported by the Karabuk University Scientific Research Projects Coordinatorship (Project No: KBUBAP-17-YL-176).en_US
dc.identifier.doi10.1016/j.molstruc.2019.127370
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85075839442en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2019.127370
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5133
dc.identifier.volume1203en_US
dc.identifier.wosWOS:000504448700016en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofJournal of Molecular Structureen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectEpoxyen_US
dc.subjectOxiraneen_US
dc.subjectComplexen_US
dc.subjectEpichlorohydrinen_US
dc.subjects-Triazineen_US
dc.subjectPolymeren_US
dc.titleThe synthesis and characterization of s-Triazine polymer complexes containing epoxy groupsen_US
dc.typeArticleen_US

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