Eco-friendly dehydrogenation of dimethylamine- borane catalyzed by core-shell-looking tri-metallic RuNiPd nanoclusters loaded on white-lowering horse-chestnut seed

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dc.authoridDUMAN, Sibel/0000-0003-1517-9800
dc.contributor.authorUlutas, Kadir
dc.contributor.authorAlshawesh, Mansour
dc.contributor.authorDuman, Sibel
dc.date.accessioned2024-09-29T15:57:20Z
dc.date.available2024-09-29T15:57:20Z
dc.date.issued2022
dc.departmentKarabük Üniversitesien_US
dc.description.abstractGenerally, white-flowering horse-chestnut seed (WFHC) found in roadsides, parks and gardens, which spills around and causes environmental pollution, is defined as waste-bio material. This study is quite remarkable as it gives WFHC a new field of usage and literally prioritizes the environment. Here, waste-bio WFHC was tested as supporter for tri-metallic RuNiPd nanoclusters in the eco-friendly dehydrogenation of dimethylamine-borane (DMAB). Core-shell-looking tri-metallic RuNiPd@WFHC, with 264.09 +/- 45.55 nm particle size, were in-situ synthesized throughout dehydrogenation of DMAB at 35.0 +/- 0.1 degrees C. The WFHC and tri-metallic Ru2.00Ni1.86Pd1.00@WFHC NCs were characterized by advanced analysis and their surface morphologies were studied in detail using adsorption models. The N2 adsorption-desorption and logarithmic-Freundlich plots indicated that surface morphologies have heterogeneous multi-layer and typical Type-III isotherm with meso-porous surfaces. Also, detailed kinetic studies were actualized on the dehydrogenation of DMAB catalyzed by tri-metallic Ru2.00Ni1.86Pd1.00@WFHC NCs with 158 h-1 TOF value.(c) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipKarabuk University Scientific Research Projects Coordination Unit; [KBUBAP-21-YL-007]en_US
dc.description.sponsorshipThe authors would like to express their gratitude to the Karabuk University Scientific Research Projects Coordination Unit for the financial assistance provided under project number KBUBAP-21-YL-007.en_US
dc.identifier.doi10.1016/j.ijhydene.2022.08.308
dc.identifier.endpage38218en_US
dc.identifier.issn0360-3199
dc.identifier.issn1879-3487
dc.identifier.issue90en_US
dc.identifier.scopus2-s2.0-85138820184en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage38198en_US
dc.identifier.urihttps://doi.org/10.1016/j.ijhydene.2022.08.308
dc.identifier.urihttps://hdl.handle.net/20.500.14619/4741
dc.identifier.volume47en_US
dc.identifier.wosWOS:000883831300009en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofInternational Journal of Hydrogen Energyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectHorse-chestnuten_US
dc.subjectAlloy-catalysten_US
dc.subjectEco-friendly dehydrogenationen_US
dc.subjectDimethylamine-boraneen_US
dc.subjectCleaner-production technologiesen_US
dc.titleEco-friendly dehydrogenation of dimethylamine- borane catalyzed by core-shell-looking tri-metallic RuNiPd nanoclusters loaded on white-lowering horse-chestnut seeden_US
dc.typeArticleen_US

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