Tetrakis[?-4-(diethylamino)benzoato-?2O:O?]bis[(N,N-diethylnicotinamide-?N1)zinc(II)]

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dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.contributor.authorHoekelek, Tuncer
dc.contributor.authorYilmaz, Filiz
dc.contributor.authorTercan, Baris
dc.contributor.authorAybirdi, Oezguer
dc.contributor.authorNecefoglu, Hacali
dc.date.accessioned2024-09-29T16:03:14Z
dc.date.available2024-09-29T16:03:14Z
dc.date.issued2009
dc.departmentKarabük Üniversitesien_US
dc.description.abstractIn the centrosymmetric binuclear title complex, [Zn-2(C11H14NO2)(4)(C10H14N2O)(2)], the two Zn-II ions [Zn center dot center dot center dot Zn = 2.8874 (3) angstrom] are bridged by four 4-(diethylamino)benzoate (DEAB) ligands. The four nearest O atoms around each Zn-II ion form a distorted square-planar arrangement, the distorted square-pyramidal coordination being completed by the pyridine N atom of an N,N-diethylnicotinamide (DENA) ligand at a distance of 2.0484 (12) angstrom. The dihedral angle between the benzene ring and the carboxylate group is 4.89 (6)degrees in one of the independent DEAB ligands and 7.13 (7)degrees in the other. The benzene rings of the two independent DEAB ligands are oriented at a dihedral angle of 86.58 (5)degrees. The pyridine ring is oriented at dihedral angles of 31.17 (4) and 58.38 (4)degrees with respect to the two benzene rings. In the crystal, weak intermolecular C-H center dot center dot center dot O interactions link the molecules into a three-dimensional network. Two weak C-H center dot center dot center dot pi interactions are also present. The two ethyl groups of one of the DEAB ligands are disordered over two orientations, with occupancy ratios of 0.798 (5): 0.202 (5) and 0.890 (5): 0.110 (5).en_US
dc.identifier.doi10.1107/S1600536809027986
dc.identifier.endpageU1245en_US
dc.identifier.issn2056-9890
dc.identifier.pmid21583403en_US
dc.identifier.scopus2-s2.0-68749107014en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpageM955en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536809027986
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5981
dc.identifier.volume65en_US
dc.identifier.wosWOS:000268510800097en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Crystallographic Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectCrystalen_US
dc.subjectCopperen_US
dc.titleTetrakis[?-4-(diethylamino)benzoato-?2O:O?]bis[(N,N-diethylnicotinamide-?N1)zinc(II)]en_US
dc.typeArticleen_US

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