Novel BODIPY-Fluorene-Fullerene and BODIPY-Fluorene-BODIPY Conjugates: Synthesis, Characterization, Photophysical and Photochemical Properties

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dc.contributor.authorSarikaya, Semiha Yildirim
dc.contributor.authorAlidagi, Husniye Ardic
dc.contributor.authorCetindere, Seda
dc.date.accessioned2024-09-29T15:51:18Z
dc.date.available2024-09-29T15:51:18Z
dc.date.issued2023
dc.departmentKarabük Üniversitesien_US
dc.description.abstractTwo new BODIPY-fluorene-fullerene (3) and BODIPY-fluorene-BODIPY (4) conjugates were designed, synthesized, and characterized for the first time. The structural properties of compounds were investigated with elemental analysis, mass, H-1, and C-13 NMR techniques. Absorption and fluorescence spectroscopy were used to examine the photophysical (absorption and emission profiles, fluorescence quantum yields, and lifetimes) and photochemical (formation of singlet oxygen (O-1(2))) properties. It was observed that the novel compounds (3) and (4) showed high molar extinction coefficients and good O-1(2) quantum yields. O-1(2) formation ability of the BODIPY-fluorene-fullerene conjugate (3) was more efficient than that of the BODIPY-fluorene-BODIPY conjugate (4). Furthermore, photosensitization ability of both conjugate systems was more remarkable than some commonly used BODIPY based photosensitizers. The data presented in this work indicate that these two novel systems are effective O-1(2) photosensitizers that might be used for various areas of applications such as photodynamic therapy and photocatalysis.en_US
dc.identifier.doi10.1007/s10895-022-03060-8
dc.identifier.endpage304en_US
dc.identifier.issn1053-0509
dc.identifier.issn1573-4994
dc.identifier.issue1en_US
dc.identifier.pmid36409387en_US
dc.identifier.scopus2-s2.0-85142362522en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage297en_US
dc.identifier.urihttps://doi.org/10.1007/s10895-022-03060-8
dc.identifier.urihttps://hdl.handle.net/20.500.14619/3999
dc.identifier.volume33en_US
dc.identifier.wosWOS:000886181800002en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherSpringer/Plenum Publishersen_US
dc.relation.ispartofJournal of Fluorescenceen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBODIPYen_US
dc.subjectFullereneen_US
dc.subjectFluoreneen_US
dc.subjectPhotophysicalen_US
dc.subjectPhotochemicalen_US
dc.subjectSinglet oxygenen_US
dc.titleNovel BODIPY-Fluorene-Fullerene and BODIPY-Fluorene-BODIPY Conjugates: Synthesis, Characterization, Photophysical and Photochemical Propertiesen_US
dc.typeArticleen_US

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