Diaquabis(4-methylaminobenzoato-?O)bis(nicotinamide-?N1)cobalt(II)
Küçük Resim Yok
Tarih
2010
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Wiley-Blackwell
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
The asymmetric unit of the title Co-II complex, [Co(C8H8NO2)(2)(C6H6N2O)(2)(H2O)(2)], contains two half complex molecules with similar structures. The Co-II atoms are each located on an inversion center and each is coordinated by two 4-methylaminobenzoate (PMAB), two nicotinamide (NA) ligands and two water molecules in a distorted octahedral coordination. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 3.0 (3) and 2.54 (19)degrees, while the pyridine and benzene rings are oriented at dihedral angles of 67.40 (8) and 66.25 (8)degrees. In the crystal structure, intermolecular O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds link the molecules into a supramolecular structure.
Açıklama
Anahtar Kelimeler
Kaynak
Acta Crystallographica Section E-Structure Reports Online
WoS Q Değeri
Q4
Scopus Q Değeri
N/A
Cilt
66
