Tetraaquabis(nicotinamide-?N1)cobalt(II) bis(2-fluorobenzoate)

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dc.authoridOzturkkan, Fureya Elif/0000-0001-6376-4161
dc.contributor.authorOzbek, F. Elif
dc.contributor.authorTercan, Baris
dc.contributor.authorSahin, Ertan
dc.contributor.authorNecefoglu, Hacali
dc.contributor.authorHokelek, Tuncer
dc.date.accessioned2024-09-29T16:03:13Z
dc.date.available2024-09-29T16:03:13Z
dc.date.issued2009
dc.departmentKarabük Üniversitesien_US
dc.description.abstractThe title complex, [Co(C6H6N2O)(2)(H2O)(4)](C7H4FO2)(2), contains one Co(II) atom (site symmetry (1) over bar), two monodentate nicotinamide (NA) ligands, four coordinated water molecules and two 2-fluorobenzoate (FB) anions. The four O atoms in the equatorial plane around the Co atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 29.8 (3)degrees, while the pyridine and benzene rings are oriented at a dihedral angle of 7.97 (12)degrees. In the crystal structure, molecules are linked by O-H center dot center dot center dot O, N-H center dot center dot center dot O and N-H center dot center dot center dot F hydrogen bonds, forming an infinite three-dimensional network. pi-pi Contacts between the pyridine and benzene rings [centroid-centroid distance = 3.673 (3) angstrom] may further stabilize the crystal structure.en_US
dc.description.sponsorshipUniversity Research Fund [2003/219]en_US
dc.description.sponsorshipThe authors are indebted to the Department of Chemistry, Ataturk University, Erzurum, Turkey, for the use of X-ray diffractometer purchased under grant No. 2003/219 of the University Research Fund.en_US
dc.identifier.doi10.1107/S1600536809006771
dc.identifier.endpageU983en_US
dc.identifier.issn2056-9890
dc.identifier.pmid21582108en_US
dc.identifier.scopus2-s2.0-62149105577en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpageM341en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536809006771
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5964
dc.identifier.volume65en_US
dc.identifier.wosWOS:000264796100078en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Structure Reports Onlineen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleTetraaquabis(nicotinamide-?N1)cobalt(II) bis(2-fluorobenzoate)en_US
dc.typeArticleen_US

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