Diaquabis(2-chlorobenzoato-?O) bis(nicotinamide-?N1)cobalt(II)

dc.authoridOzturkkan, Fureya Elif/0000-0001-6376-4161
dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.contributor.authorDincel, Oznur
dc.contributor.authorTercan, Bans
dc.contributor.authorOzturkkan, Fureya Elif
dc.contributor.authorNecefoglu, Hacali
dc.contributor.authorHokelac, Tuncer
dc.date.accessioned2024-09-29T16:03:23Z
dc.date.available2024-09-29T16:03:23Z
dc.date.issued2013
dc.departmentKarabük Üniversitesien_US
dc.description.abstractIn the title complex, [Co(C7H4ClO2)(2)(C6H6N2O)(2)(H2O)(2)], the Co II cation is located on an inversion center and is coordinated by two 2-chlorobenzoate anions, two nicotinamide (NA) ligands and two water molecules. The four O atoms in the equatorial plane around the Co II cation form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 29.7 (4)degrees, while the pyridine and benzene rings are oriented at a dihedral angle of 83.17 (15)degrees. Intramolecular O-H center dot center dot center dot O hydrogen bonding occurs between the carboxylate group and coordinating water molecule. In the crystal, intermolecular N-H center dot center dot center dot O, O-H center dot center dot center dot O and weak C-H center dot center dot center dot O hydrogen bonds link the molecules into a three-dimensional network.en_US
dc.description.sponsorshipKafkas University Research Fund [2009-FEF-03]en_US
dc.description.sponsorshipThe authors are indebted to Anadolu University and the Medicinal Plants and Medicine Research Centre of Anadolu University, Eskis, ehir, Turkey, for the use of X-ray diffractometer. This work was supported financially by Kafkas University Research Fund (grant No. 2009-FEF-03).en_US
dc.identifier.doi10.1107/S1600536813004984
dc.identifier.endpage+en_US
dc.identifier.issn2056-9890
dc.identifier.pmid23476513en_US
dc.identifier.scopus2-s2.0-84874828363en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpageM173en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536813004984
dc.identifier.urihttps://hdl.handle.net/20.500.14619/6039
dc.identifier.volume69en_US
dc.identifier.wosWOS:000421582100035en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Structure Reports Onlineen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleDiaquabis(2-chlorobenzoato-?O) bis(nicotinamide-?N1)cobalt(II)en_US
dc.typeArticleen_US

Dosyalar