Diaquabis(4-methoxybenzoato-?O 1)bis(nicotinamide-?N 1)cobalt(II) dihydrate

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dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.contributor.authorHokelek, Tuncer
dc.contributor.authorDal, Hakan
dc.contributor.authorTercan, Baris
dc.contributor.authorTenlik, Erdinc
dc.contributor.authorNecefoglu, Hacali
dc.date.accessioned2024-09-29T16:03:18Z
dc.date.available2024-09-29T16:03:18Z
dc.date.issued2010
dc.departmentKarabük Üniversitesien_US
dc.description.abstractIn the mononuclear title compound, [Co(C8H7O3)(2)(C6H6N2O)(2)(H2O)(2)]center dot 2H(2)O, the CoII ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 4-methoxybenzoate anion, one nicotinamide (NA) ligand and one coordinated and one uncoordinated water molecule. All ligands act in a monodentate mode. The four O atoms in the equatorial plane around the CoII ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the attached benzene ring is 6.47 (7)degrees, while the pyridine and benzene rings are oriented at a dihedral angle of 72.80 (4)degrees. An O-H...O hydrogen bond links the uncoordinated water molecule to one of the carboxylate groups. In the crystal structure, intermolecular O-H...O, N-H...O and C-H...O hydrogen bonds link the molecules into a three-dimensional network.en_US
dc.description.sponsorshipKafkas University [2009-FEF-03]en_US
dc.description.sponsorshipThe authors are indebted to Anadolu University and the Medicinal Plants and Medicine Research Centre of Anadolu University, Eskisehir, Turkey, for the use of thediffractometer. This work was supported financially by Kafkas University Research Fund (grant No. 2009-FEF-03).en_US
dc.identifier.doi10.1107/S1600536810026462
dc.identifier.endpageU480en_US
dc.identifier.issn2056-9890
dc.identifier.pmid21588149en_US
dc.identifier.scopus2-s2.0-77956329176en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpageM910en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536810026462
dc.identifier.urihttps://hdl.handle.net/20.500.14619/6013
dc.identifier.volume66en_US
dc.identifier.wosWOS:000282468400042en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Crystallographic Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleDiaquabis(4-methoxybenzoato-?O 1)bis(nicotinamide-?N 1)cobalt(II) dihydrateen_US
dc.typeArticleen_US

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